A smart DOPO ‐containing decoration armed on Salen‐polyphosphazene toward high‐efficient flame retardancy for epoxy thermoset

Author(s):  
Baoping Yang ◽  
Pengju Zhao ◽  
Yongliang Guo ◽  
Xin Mao ◽  
Ting Li ◽  
...  
2013 ◽  
Vol 650 ◽  
pp. 279-284 ◽  
Author(s):  
Xiao Dan Lin ◽  
Bin Yang ◽  
Guang Kai Wang ◽  
Erigene Bakangura ◽  
Ming Huang ◽  
...  

Non halogen flame retardant researches have achieved great progress; however, theoretical works are much lagged. Here we show a model of an efficient Flame Retardant Carpet (e-FRC) based on the synergistic flame retardant system of phosphorus and hydroxyl compounds that can give ABS UL 94 V-0 efficiently. This model is further extended to explain the high efficient flame retardancy of phosphonates by proposing a surfactant structured intermediate from pyrolysis. The smart intermediate self-assembles on charred polymer matrix, forming an anisotropy molecular membrane, with one side of hydrocarbon groups and the other of inorganic groups. The organic side adheres onto polymeric char, and inorganic side facing the fire, forms an Oxygen Shielding Screen (OSS). The OSS together with charred layer underneath constitutes an e-FRC. This e-FRC structure can be found in earlier reports. It can explain all present existing efficient flame retardant systems.


Vestnik MEI ◽  
2018 ◽  
Vol 6 (6) ◽  
pp. 33-42
Author(s):  
Pavel V. Roslyakov ◽  
◽  
Bronislav G. Grisha ◽  
Igor L. Ionkin ◽  
Mikhail N. Zaichenko ◽  
...  

2020 ◽  
Author(s):  
Yamin Zhang ◽  
Zhongpu Wang ◽  
Deping Li ◽  
Qing Sun ◽  
Kangrong Lai ◽  
...  

<p></p><p>Porous carbon has attracted extensive attentions as the electrode material for various energy storage devices considering its advantages like high theoretical capacitance/capacity, high conductivity, low cost and earth abundant inherence. However, there still exists some disadvantages limiting its further applications, such as the tedious fabrication process, limited metal-ion transport kinetics and undesired structure deformation at harsh electrochemical conditions. Herein, we report a facile strategy, with calcium gluconate firstly reported as the carbon source, to fabricate ultrathin porous carbon nanosheets. <a>The as-prepared Ca-900 electrode delivers excellent K-ion storage performance including high reversible capacity (430.7 mAh g<sup>-1</sup>), superior rate capability (154.8 mAh g<sup>-1</sup> at an ultrahigh current density of 5.0 A g<sup>-1</sup>) and ultra-stable long-term cycling stability (a high capacity retention ratio of ~81.2% after 4000 cycles at 1.0 A g<sup>-1</sup>). </a>Similarly, when being applied in Zn-ion capacitors, the Ca-900 electrode also exhibits an ultra-stable cycling performance with ~90.9% capacity retention after 4000 cycles at 1.0 A g<sup>-1</sup>, illuminating the applicable potentials. Moreover, the origin of the fast and smooth metal-ion storage is also revealed by carefully designed consecutive CV measurements. Overall, considering the facile preparation strategy, unique structure, application flexibility and in-depth mechanism investigations, this work will deepen the fundamental understandings and boost the commercialization of high-efficient energy storage devices like potassium-ion/sodium-ion batteries, zinc-ion batteries/capacitors and aluminum-ion batteries.</p><br><p></p>


2018 ◽  
Author(s):  
Riva Alkarsifi ◽  
Florent Pourcin ◽  
Pavlo Perkhun ◽  
Mats Fahlman ◽  
Christine Videlot-Ackermann ◽  
...  

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