Reactions of Coinage Metal Salts with a Mixed Sulfonic/Carboxylic Acid Anhydride

2007 ◽  
Vol 633 (13-14) ◽  
pp. 2431-2434 ◽  
Author(s):  
Weifeng Shi ◽  
Le Zhang ◽  
Maryam Shafaei-Fallah ◽  
Alexander Rothenberger
Keyword(s):  
Carboxylic Acid ◽  
Acid Anhydride ◽  
Metal Salts ◽  
Coinage Metal ◽  
Carboxylic Acid Anhydride

Titrimetric analysis of carboxylic acid-anhydride mixtures with tetrabutylammonium hydroxide

1974 ◽  
Vol 46 (9) ◽  
pp. 1331-1334 ◽  
Author(s):  
C. A. Lucchesi ◽  
L. W. Kao ◽  
G. A. Young ◽  
H. M. Chang
Keyword(s):  
Carboxylic Acid ◽  
Acid Anhydride ◽  
Tetrabutylammonium Hydroxide ◽  
Carboxylic Acid Anhydride

Darstellung und Reaktionen der Oxovanadin(V)-tricarboxylate / Synthesis and Reactions of Oxovanadium(V) Tricarboxylates

1980 ◽  
Vol 35 (7) ◽  
pp. 817-823 ◽  
Author(s):  
Fritz Preuss ◽  
Willi Towae ◽  
Joachim Woitschach
Keyword(s):  
Nmr Spectroscopy ◽  
Carboxylic Acid ◽  
Complex Formation ◽  
Chemical Reactions ◽  
Acid Anhydride ◽  
Carboxylate Ligands ◽  
H Nmr ◽  
Silver Carboxylate ◽  
Carboxylic Acid Anhydride

Monomeric oxovanadium(V) tricarboxylates VO(RCOO)3 are prepared by reaction of VOCl3 with an excess of silver carboxylate in CH2Cl2 or by depolymerization of (VO2RCOO)n in carboxylic acid anhydride. Their properties are studied by IR and 1H NMR spectroscopy as well as by chemical reactions such as thermolysis, solvolysis, redistribution and complex formation. The structure of 2,2′-dipyridyl and 1,10-phenanthroline complexes [VO(RCOO)3 · B] (B = C10H8N2, C12H8N2) has been found to be octahedral with meridional arrangement of the carboxylate ligands. Syntheses of Na[VO(CH3COO)4] and Ba[VO2(CH3COO)3] · 2CH3COOH are described

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