Alkaline-earth Metal Nitrides of the Main-Group Elements: Crystal Structures and Properties of Inverse Perovskites

2013 ◽  
Vol 639 (10) ◽  
pp. 1699-1715 ◽  
Author(s):  
Rainer Niewa
Keyword(s):  
Crystal Structures ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Main Group ◽  
Alkaline Earth Metal ◽  
Metal Nitrides ◽  
Main Group Elements ◽  
Structures And Properties

scholarly journals Die Kristallstrukturen von Strontium- und Bariumhexacyanoferrat(III)-Hexamethylentetramin-Hydraten. Strukturmodell für Additionsverbindungen der Alkali- und Erdalkalimetallhexacyanoferrate mit Hexamethylentetramin / The Crystal Structures of Hydrates of Strontium and Barium Hexacyanoferrate(III) with Hexamethylenetetramine. Structural Model for Adducts of the Hexacyanoferrates of Alkaline and Alkaline Earth Metals with Hexamethylenetetramine

1989 ◽  
Vol 44 (5) ◽  
pp. 519-525 ◽  
Author(s):  
Hans-Jürgen Meyer ◽  
Joachim Pickardt
Keyword(s):  
Aqueous Solutions ◽  
Crystal Structures ◽  
General Formula ◽  
Alkaline Earth ◽  
Structural Model ◽  
Earth Metal ◽  
Alkaline Earth Metals ◽  
Alkaline Earth Metal ◽  
Monoclinic Space Group ◽  
Space Group

By reaction of methanolic solutions of hexamethylenetetramine with aqueous solutions of hexacyanoferrates(III) of strontium and barium resp., crystals of the compounds were obtained. Sr3[Fe(CN)6]2 · 3 C6H12N4 · 18 H2O, tetragonal, space group P42/nmc, Z = 4, a = 1931.8(4), c = 1579.9(4) pm, 1358 reflections. R = 0.066. Ba3[Fe(CN)6]2 · 2 C6H12N4 · 11 Η2Ο. monoclinic. space group P21/n, Ζ = 2, a = 1148.0(4), b = 1369.7(4), c = 1584.5(4) pm, γ = 95.79(3)°, 2583 reflections, R = 0.057. The crystal structures of these adducts are compared with those of other hexamethylenetetramine adducts of alkaline and alkaline earth metal hexacyanoferrates of the general formula M,[Fe(CN)6]y · zC6H12N4 · vH2O recently investigated by us. A structural model for the adducts is presented.

Syntheses, Structures, and Properties of Two-Dimensional Alkaline Earth Metal Complexes with Flexible Tripodal Tricarboxylate Ligands

2005 ◽  
Vol 5 (1) ◽  
pp. 177-182 ◽  
Author(s):  
Hui-Fang Zhu ◽  
Zheng-Hua Zhang ◽  
Wei-Yin Sun ◽  
Taka-aki Okamura ◽  
Norikazu Ueyama
Keyword(s):  
Metal Complexes ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Two Dimensional ◽  
Structures And Properties
Sign in / Sign up

Export Citation Format

Share Document