Karamanos, R., Hanson, K. and Stevenson, F. C. 2014. Nitrogen form, time and rate of application, and nitrification inhibitor effects on crop production. Can. J. Plant Sci. 94: 425–432. Nitrogen management options for anhydrous ammonia (NH3) and urea were compared in a barley–wheat–canola–wheat cropping sequence (2007–2010) at Watrous and Lake Lenore, SK. The treatment design included a factorial arrangement of N fertilizer form (NH3versus urea), nitrification inhibitor application, time of N application (mid-September, mid- to late October, and spring) and four N fertilizer rates (0, 40, 80 and 120 kg ha−1). Anhydrous ammonia applications at 40 kg N ha−1in 2008 (fall) and in 2010 (all times of application) resulted in wheat yield reductions relative to the same applications for urea. For wheat years, yield was reduced for both fall versus spring N fertilizer applications, when no nitrification inhibitor was applied and the inclusion of nitrification inhibitor maintained wheat yield at similar levels across all times of N fertilizer applications, regardless of form. Protein concentration was approximately 2 g kg−1greater with urea compared with NH3at both sites in 2008 and only at Watrous in 2010. Also, early versus late fall N fertilizer applications consistently increased N concentration of grain only for the 40 and/or 80 kg N ha−1rates. Effects of nitrification inhibitor on N concentration were not frequent and appeared to be minimal. Urea had greater agronomic efficiency (AE) than NH3at the lower N fertilizer rates. The nitrification inhibitor had a positive effect on wheat AE only for early fall N fertilizer applications. It can be concluded that for maximum yields NH3or urea will be suitable if applied at rates of 80 kg N ha−1and greater. If N fertilizer is applied at 40 kg N ha−1, especially in fall without inhibitor, urea is better. In terms of protein concentration for wheat, urea seemed to better than NH3and fall was better than spring application.
Rb
2
[U(NH
2
)
6
], a Rubidium Hexaamidouranate(IV) obtained from the Reaction of UI
3
with RbNH
2
in Anhydrous Ammonia
