Kinetics and Mechanism of Steady-State Catalytic NO Decomposition Reactions on Cu–ZSM5

2002 ◽  
Vol 209 (1) ◽  
pp. 75-86 ◽  
Author(s):  
Björn Modén ◽  
Patrick Da Costa ◽  
Benjamin Fonfé ◽  
Deuk Ki Lee ◽  
Enrique Iglesia
2005 ◽  
Vol 236 (1-2) ◽  
pp. 182-186 ◽  
Author(s):  
Junjiang Zhu ◽  
Dehai Xiao ◽  
Jing Li ◽  
Xiangguang Yang ◽  
Yue Wu

2010 ◽  
Vol 315 (2) ◽  
pp. 155-162 ◽  
Author(s):  
A.K. Avetisov ◽  
J.R. Rostrup-Nielsen ◽  
V.L. Kuchaev ◽  
J.-H. Bak Hansen ◽  
A.G. Zyskin ◽  
...  

2005 ◽  
Vol 5 (4) ◽  
pp. 5645-5667
Author(s):  
S. Seisel ◽  
C. Börensen ◽  
R. Vogt ◽  
R. Zellner

Abstract. The heterogeneous reaction of N2O5 with mineral (Saharan) dust has been studied at T=298 K using a combination of Knudsen and DRIFTS cell for kinetic and product investigations, respectively. The initial uptake coefficient has been determined to be γ=(8.0±0.3)·10−2. This uptake slowly saturates into a steady state uptake of γ=(1.3±0.3)10−2 suggesting that reaction of N2O5 with the mineral dust surface and hydrolysis of N2O5 on the surface take place simultaneously. Moreover, the product investigations suggest that N2O5 is irreversibly taken up forming nitrate on the surface. The uptake rates of N2O5 on Saharan dust are large enough to influence the photo-oxidant budget of the atmosphere.


2004 ◽  
Vol 221 (1-2) ◽  
pp. 127-136 ◽  
Author(s):  
Rui Marques ◽  
Pierre Darcy ◽  
Patrick Da Costa ◽  
Henry Mellottée ◽  
Jean-Michel Trichard ◽  
...  

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