Design and Applications of Multiscale Organic–Inorganic Hybrid Materials Derived from Block Copolymer Self-Assembly

Author(s):  
Kahyun Hur ◽  
Ulrich Wiesner
2013 ◽  
Vol 538 ◽  
pp. 181-184 ◽  
Author(s):  
Xin De Tang ◽  
Ye Chen ◽  
Fa Qi Yu ◽  
Mei Shan Pei

Organic/inorganic hybrid materials based upon stimuli-responsive copolymers have attracted an inceasing attention. Compared with the polymeric materials, these hybrid materials can form aggregates in aqueous solution with much more stable shape-persistance due to the inorganic structure, which facilitate the mass delivery and long-term life. A novel hybrid material based on a new reactive block copolymer, poly(ethylene oxide)-block-poly{3-(trimethoxysilyl)propyl methacrylate-co-N-isopropylacrylamide-co-6-[4-(4-methoxyphenylazo)phenoxy]hexyl methacrylate} [PEO-P(TMSPMA-NIPAM-AzoMA)] was synthesized via atom transfer radical polymerization (ATRP). The vesicles were obtained by self-assembly of the resulting block copolymer in a selective solvent, and then the PTMSPMA block was subjected to hydrolysis and polycondensation reaction to fix vesicle wall in the presence of triethylamine as a catalyst. The photo- and thermo- dual-responsive properties of the vesicles were investigated.


2020 ◽  
Vol 32 (9) ◽  
pp. 3680-3700 ◽  
Author(s):  
Vincent J. Pastore ◽  
Timothy R. Cook

RSC Advances ◽  
2015 ◽  
Vol 5 (73) ◽  
pp. 59093-59098 ◽  
Author(s):  
Xiao Li ◽  
Liu Yang ◽  
Chao Qin ◽  
Fu-Hong Liu ◽  
Liang Zhao ◽  
...  

Four new polyoxovanadate-based organic–inorganic hybrid materials have been synthesized under hydrothermal conditions through self-assembly. Their thermal stabilities and photocatalytic activities were also investigated.


2009 ◽  
Vol 52 (11) ◽  
pp. 1759-1768 ◽  
Author(s):  
LeLe Li ◽  
LingDong Sun ◽  
YaWen Zhang ◽  
ChunHua Yan

2015 ◽  
Vol 7 (23) ◽  
pp. 12440-12449 ◽  
Author(s):  
Torsten Pietsch ◽  
Peter Müller-Buschbaum ◽  
Boris Mahltig ◽  
Amir Fahmi

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