Structurally Characterized Transition-Metal Phosphine Complexes of Relevance to Catalytic Reactions

1983 ◽  
pp. 111-135 ◽  
Author(s):  
Nancy L. Jones ◽  
James A. Ibers
Keyword(s):  
Transition Metal ◽  
Catalytic Reactions ◽  
Phosphine Complexes

Active site engineering of atomically dispersed transition metal-heteroatom-carbon catalysts for oxygen reduction

2021 ◽  
Author(s):  
Jiawei Zhu ◽  
Shichun Mu
Keyword(s):  
Transition Metal ◽  
Oxygen Reduction ◽  
Active Site ◽  
Catalytic Reactions ◽  
Single Atom ◽  
Carbon Catalysts

Owing to the advantage of atomic utilization, the single-atom catalyst has attracted much attention and been employed in multifarious catalytic reactions. Their definite site configuration is favorable for exploring the...

Cooperative Catalytic Reactions Using Organocatalysts and Transition Metal Catalysts: Enantioselective Propargylic Alkylation of Propargylic Esters with Aldehydes

2011 ◽  
Vol 13 (4) ◽  
pp. 592-595 ◽  
Author(s):  
Akiko Yoshida ◽  
Masahiro Ikeda ◽  
Gaku Hattori ◽  
Yoshihiro Miyake ◽  
Yoshiaki Nishibayashi
Keyword(s):  
Transition Metal ◽  
Metal Catalysts ◽  
Transition Metal Catalysts ◽  
Catalytic Reactions ◽  
Propargylic Esters

Metal-Ligand Cooperative Approaches in Homogeneous Catalysis Using Transition Metal Complex Catalysts of Redox Noninnocent Ligands

2021 ◽  
Author(s):  
Rakesh Mondal ◽  
Amit Kumar Guin ◽  
Gargi Chakraborty ◽  
Nanda D Paul
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Homogeneous Catalysis ◽  
Transition Metal Complex ◽  
Raw Materials ◽  
Value Added ◽  
Catalytic Reactions ◽  
Redox Noninnocent ◽  
Metal Ligand ◽  
Metal Complex Catalysts

Catalysis offers a straightforward route to prepare various value-added molecules starting from readily available raw materials. The catalytic reactions mostly involve multi-electron transformations. Hence, compared to the inexpensive and readily...

Hydrogenation of Olefins, Alkynes, Allenes, and Arenes by Borane-based Frustrated Lewis Pairs

Synthesis ◽  
2021 ◽  
Author(s):  
Felix Wech ◽  
Urs Gellrich
Keyword(s):  
Transition Metal ◽  
Hydride Transfer ◽  
Lewis Base ◽  
Catalytic Reactions ◽  
Transfer Reactions ◽  
Organic Substrates ◽  
Frustrated Lewis Pairs ◽  
Hydrogen Activation ◽  
Hydrogenation Catalysts ◽  
Lewis Pairs

In recent years, borane-based frustrated Lewis pairs proved to be efficient hydrogenation catalysts and became an alternative to transition metal-based systems. The hydrogen activation by classic FLPs leads to a protonated Lewis base and a borohydride. Consequently, hydrogenations catalyzed by classic FLPs consist of stepwise hydride transfer reactions and protonations (or vice versa). More recently, systems that operate via an initial hydroboration have allowed extending the substrate scope for FLP catalyzed hydrogenations. Within this review, hydrogenations of organic substrates catalyzed by borane-based frustrated Lewis pairs are discussed. Emphasis is given to the mechanistic aspects of these catalytic reactions.

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