Mining and Processing of Seafloor Massive Sulfides: Experiences and Challenges

2022 ◽  
pp. 167-197
Author(s):  
Seiya Kawano ◽  
Hisatoshi Furuya
Keyword(s):  
Author(s):  
Yasuharu Nakajima ◽  
Shotaro Uto ◽  
Shigeo Kanada ◽  
Joji Yamamoto ◽  
Ichihiko Takahashi ◽  
...  

Seafloor Massive Sulfides (SMS), which were formed by deposition of precipitates from hydrothermal fluids vented from seafloor, is one of unconventional mineral resources beneath deep seafloors in the world. The authors have proposed the concept of seafloor mineral processing for development of SMS, where useful minerals included in SMS ores are separated on seafloor to be lifted while the remaining gangue is disposed on seafloor in appropriate ways. To apply column flotation, one of conventional methods in mineral processing, to seafloor mineral processing, the authors carried out simulating experiments of column flotation on deep seafloor using ores including copper, iron, lead and zinc as metallic elements. Prior to the experiments at high pressures, preparatory experiments at the atmospheric pressure were carried out to find out the optimum condition of the properties of pulp, a mixture of feed ore, water and chemical reagents. In flotation experiments at high pressures, formation and overflow of froth layer by bubbling were observed at 1MPa in both of pulps with pure water and artificial seawater. The analytical data showed that the concentration of metallic elements such as copper and zinc in the concentrates recovered from the experiments was higher than that in the feed ores while the concentration of silicon and calcium, which are assigned to gangue, in the concentrates was lower than that in the feed ores. These results suggest that column flotation can be applied to operation on seafloor.


Geophysics ◽  
2000 ◽  
Vol 65 (6) ◽  
pp. 1882-1889 ◽  
Author(s):  
Matthew H. Salisbury ◽  
Bernd Milkereit ◽  
Graham Ascough ◽  
Robin Adair ◽  
Larry Matthews ◽  
...  

Laboratory studies show that the acoustic impedances of massive sulfides can be predicted from the physical properties ([Formula: see text], density) and modal abundances of common sulfide minerals using simple mixing relations. Most sulfides have significantly higher impedances than silicate rocks, implying that seismic reflection techniques can be used directly for base metals exploration, provided the deposits meet the geometric constraints required for detection. To test this concept, a series of 1-, 2-, and 3-D seismic experiments were conducted to image known ore bodies in central and eastern Canada. In one recent test, conducted at the Halfmile Lake copper‐nickel deposit in the Bathurst camp, laboratory measurements on representative samples of ore and country rock demonstrated that the ores should make strong reflectors at the site, while velocity and density logging confirmed that these reflectors should persist at formation scales. These predictions have been confirmed by the detection of strong reflections from the deposit using vertical seismic profiling and 2-D multichannel seismic imaging techniques.


Author(s):  
Satoru TAKANO ◽  
Masao ONO ◽  
Sotaro MASANOBU

Author(s):  
Yasuharu Nakajima ◽  
Yuta Yamabe ◽  
Toyohisa Fujita ◽  
Gjergj Dodbiba

Abstract This paper addresses the applicability of liquid-liquid extraction for separating mineral particles by the difference in oil-water partition coefficient, for the seafloor mineral processing of Seafloor Massive Sulfides (SMSs). Measurements of contact angle of sulfide mineral – aqueous solution – oil systems under high-pressure conditions were performed to evaluate the efficiency of liquid-liquid extraction at high pressures. The results showed that the contact angle stayed around 80 - 100° at the pressure range up to 16MPa; and the changes in the contact angles were within 5° with varying pressure. Extraction experiments were carried out by using particles of an SMS ore, which contained Zinc (Zn), Lead (Pb), and Barium (Ba) in the grade of more than 10 mass% and Copper (Cu) in a small percentage, to evaluate the beneficiation performance of liquid-liquid extraction. In the experiments, extraction conditions such as the dosage of chemical reagents, and pH in the aqueous solution were varied to optimize both the recovery and selectivity of Cu, Zn, and Pb in the oil phase, and those of Ba in the water phase. The experimental results showed that the optimum condition was 200 g/t dosage - pH 7, where the grade and recovery were ca. 37 mass% and ca. 90 mass%, respectively. The beneficiation performance of liquid-liquid extraction would be comparable to that of flotation, adapted to the processing of other SMS ores.


Geophysics ◽  
1995 ◽  
Vol 60 (2) ◽  
pp. 365-373 ◽  
Author(s):  
Anton W. Kepic ◽  
Michael Maxwell ◽  
R. Don Russell

An underground test of a seismoelectric prospecting method for massive sulfides was performed at the Mobrun Mine (Rouyn‐Noranda, Quebec) in June 1991. The method is based upon the conversion of seismic energy to high‐frequency pulses of electromagnetic radiation by sulfide minerals. The delay between shot detonation and detection of the electromagnetic radiation gives a one‐way traveltime for the acoustic wave to reach the zone of seismoelectric conversion, which when combined with P‐wave velocity allows the shot‐to‐ore zone distance to be calculated. A 0.22-kg explosive charge located within 50 m of the orebody provided the seismic excitation, and the resulting electromagnetic emissions were received by electric dipole and induction‐coil antennas. First‐arrival information from a 35‐shot survey above an orebody, the 1100 lens, provides firm evidence that short duration pulses of electromagnetic radiation are produced by the passage of acoustic waves through the orebody. The survey also demonstrated that seismoelectric conversions could be induced at shot‐to‐orebody distances of 50 m and detected at distances of up to 150 m from the orebody. Areas of seismoelectric conversion are highlighted in sections produced by plotting the position of seismic wavefronts during signal reception. The sections show anomalies that correlate with the known structure and location of the orebody and demonstrate the potential of using this seismoelectric phenomenon as an exploration tool.


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