Self-organized Chiral Liquid Crystalline Nanostructures for Energy-Saving Devices

Author(s):  
Zhigang Zheng ◽  
Quan Li
2021 ◽  
Vol 2 (1) ◽  
Author(s):  
Pedro E. S. Silva ◽  
Ricardo Chagas ◽  
Susete N. Fernandes ◽  
Pawel Pieranski ◽  
Robin L. B. Selinger ◽  
...  

AbstractCellulose-based systems are useful for many applications. However, the issue of self-organization under non-equilibrium conditions, which is ubiquitous in living matter, has scarcely been addressed in cellulose-based materials. Here, we show that quasi-2D preparations of a lyotropic cellulose-based cholesteric mesophase display travelling colourful patterns, which are generated by a chemical reaction-diffusion mechanism being simultaneous with the evaporation of solvents at the boundaries. These patterns involve spatial and temporal variation in the amplitude and sign of the helix´s pitch. We propose a simple model, based on a reaction-diffusion mechanism, which simulates the observed spatiotemporal colour behaviour.


2016 ◽  
Vol 24 (4) ◽  
Author(s):  
P. Moszczyński ◽  
A. Walczak ◽  
P. Marciniak

AbstractIn cyclic articles previously published we described and analysed self-organized light fibres inside a liquid crystalline (LC) cell contained photosensitive polymer (PP) layer. Such asymmetric LC cell we call a hybrid LC cell. Light fibre arises along a laser beam path directed in plane of an LC cell. It means that a laser beam is parallel to photosensitive layer. We observed the asymmetric LC cell response on an external driving field polarization. Observation has been done for an AC field first. It is the reason we decided to carry out a detailed research for a DC driving field to obtain an LC cell response step by step. The properly prepared LC cell has been built with an isolating layer and garbage ions deletion. We proved by means of a physical model, as well as a numerical simulation that LC asymmetric response strongly depends on junction barriers between PP and LC layers. New parametric model for a junction barrier on PP/LC boundary has been proposed. Such model is very useful because of lack of proper conductivity and charge carriers of band structure data on LC material.


Langmuir ◽  
2012 ◽  
Vol 28 (7) ◽  
pp. 3576-3582 ◽  
Author(s):  
Seock Hwan Kang ◽  
Jun-Hee Na ◽  
Sung Nam Moon ◽  
Woo Il Lee ◽  
Pil J. Yoo ◽  
...  

2015 ◽  
Vol 44 (2) ◽  
pp. 126-128 ◽  
Author(s):  
Kyosuke Isoda ◽  
Tomonori Abe ◽  
Ippei Kawamoto ◽  
Makoto Tadokoro

2008 ◽  
Vol 47-50 ◽  
pp. 165-168 ◽  
Author(s):  
Suk Wah Tam-Chang ◽  
Delfin Mahinay ◽  
Li Ming Huang

In this paper, we described the synthesis of N,N’-di-(2-ammoniumethyl)perylene- 3,4,9,10-bis(dicarboximide) ditrifluoroacetate (1), an ionic organic compound that self-organized to give chromonic liquid crystals and anisotropic crystals. Using a polymer template with micrometer-scale features to direct the ordered arrangement of 1, patterned structure with micrometer-scale local order was fabricated. The anisotropic (direction-dependent) properties of the crystals and micropatterns of 1 were investigated.


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