Viscosity and Density Measurements of High Temperature Melts

Author(s):  
Yuzuru Sato
1997 ◽  
Vol 481 ◽  
Author(s):  
Michael F. Bell ◽  
Georges Dénès ◽  
Zhimeng Zhu

ABSTRACTPrecipitation reactions from aqueous solutions of calcium nitrate and tin(II) fluoride result in the formation of two metastable phases, depending on the reaction conditions. Crystalline CaSn2F6 and the microcrystalline Ca1-xSnxF2 solid solution are obtained, the latter crystallizing in the cubic fluorite (CaF2) type with total Ca/Sn disorder. Both phases are fluoride ion conductors. Electrical conductivity measurements versus temperature and bulk density measurements show that both phases are far from thermodynamic equilibrium at ambient conditions, and thus are metastable. Both decompose to a mixture of SnF2 and CaF2 at high temperature. In addition, CaSn2F6 is chemically unstable in an aqueous medium, in which it looses SnF2 to give the microcrystalline Ca1-xSnxF2 solid solution.


2017 ◽  
Vol 658 ◽  
pp. 14-23 ◽  
Author(s):  
Javid Safarov ◽  
Felix Lesch ◽  
Khagani Suleymanli ◽  
Abilgani Aliyev ◽  
Astan Shahverdiyev ◽  
...  

CrystEngComm ◽  
2014 ◽  
Vol 16 (32) ◽  
pp. 7575-7579 ◽  
Author(s):  
Yong Chan Cho ◽  
Bum-Su Kim ◽  
Hanbyeol Yoo ◽  
Ji Young Kim ◽  
Seunghun Lee ◽  
...  

By using grain-free single crystal specimens, the melting of Cu and Ag using electrostatic levitation (ESL) and obtaining their high-temperature densities were accomplished for the first time.


2010 ◽  
Vol 294 (1-2) ◽  
pp. 131-138 ◽  
Author(s):  
Mohammad Tariq ◽  
Ana P. Serro ◽  
José L. Mata ◽  
Benilde Saramago ◽  
José M.S.S. Esperança ◽  
...  

1966 ◽  
Vol 49 (11) ◽  
pp. 624-624 ◽  
Author(s):  
L. M. ATLAS ◽  
G. J. SCHLEHMAN ◽  
D. W. READEY

2005 ◽  
Vol 86 (15) ◽  
pp. 151901 ◽  
Author(s):  
Paul-François Paradis ◽  
Takehiko Ishikawa ◽  
Shinichi Yoda

AIAA Journal ◽  
1998 ◽  
Vol 36 ◽  
pp. 1216-1222
Author(s):  
L. Y. Jiang ◽  
J. P. Sislian

1986 ◽  
Vol 64 (7) ◽  
pp. 1278-1285 ◽  
Author(s):  
Preet P. S. Saluja ◽  
Kenneth S. Pitzer ◽  
Ramesh C. Phutela

Comprehensive equations for the thermodynamic properties of aqueous NaI, CsF, CsCl, CsI, NaIO3, KIO3, CsIO3, KClO4, and HCl are generated by combining the heat capacity and density measurements reported by the first author with literature data for the enthalpy and Gibbs energy, or activity, as a function of molality at 298 K. The composition dependence is represented by the equations of Pitzer, which combine a theoretical form and Debye–Hückel terms with empirically evaluated parameters for short-range ion interactions. Temperature dependencies are represented by simple empirical equations, which should be reliable to 413 K or a little higher.


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