Methyl Internal Rotation in Substituted Toluenes

Author(s):  
Kueih-Tzu Lu ◽  
Erik C. Richard ◽  
Robert A. Walker ◽  
James C. Weisshaar
1995 ◽  
Vol 102 (17) ◽  
pp. 6787-6805 ◽  
Author(s):  
Kueih‐Tzu Lu ◽  
Frank Weinhold ◽  
James C. Weisshaar

ChemInform ◽  
2010 ◽  
Vol 31 (28) ◽  
pp. no-no
Author(s):  
Kueih-Tzu Lu ◽  
Erik C. Richard ◽  
Robert A. Walker ◽  
James C. Weisshaar

Author(s):  
Erik C. Richard ◽  
Kueih-Tzu Lu ◽  
Robert A. Walker ◽  
James C. Weisshaar

1967 ◽  
Vol 22 (11) ◽  
pp. 1738-1743 ◽  
Author(s):  
H. D. Rudolph ◽  
H. Dreizler ◽  
H. Seiler

The microwave rotational spectrum of 4-methyl-pyridine (γ-picoline) has been investigated in the region from 8 to 37 GHz. The three types of lines to be expected for a molecule of this symmetry and with a very low sixfold barrier hindering internal rotation of the methyl top have been found: m=0; | m | ≠0, ≠ 3 n; | m |=3 n. From low-/ lines m=0 (a-type transitions) the rotational constants A′ (less methyl top) =6 082.145, B=2 524.850, C=1 783.991 MHz, the dipole moment μα=2.70 D, and the nuclear quadrupole coupling constants for the 14N nucleus χaa= —4.82, χbb—χcc= —2.8 MHz have been determined. From the wide splitting of the lines | m | = 3, | K | = 1 the potential barrier has been derived as V6=13.51 cal/mole, a value which is very close to those previously deduced for toluene and para-substituted toluenes.


2000 ◽  
Vol 179 ◽  
pp. 379-380
Author(s):  
Gaetano Belvedere ◽  
Kirill Kuzanyan ◽  
Dmitry Sokoloff

Extended abstractHere we outline how asymptotic models may contribute to the investigation of mean field dynamos applied to the solar convective zone. We calculate here a spatial 2-D structure of the mean magnetic field, adopting real profiles of the solar internal rotation (the Ω-effect) and an extended prescription of the turbulent α-effect. In our model assumptions we do not prescribe any meridional flow that might seriously affect the resulting generated magnetic fields. We do not assume apriori any region or layer as a preferred site for the dynamo action (such as the overshoot zone), but the location of the α- and Ω-effects results in the propagation of dynamo waves deep in the convection zone. We consider an axially symmetric magnetic field dynamo model in a differentially rotating spherical shell. The main assumption, when using asymptotic WKB methods, is that the absolute value of the dynamo number (regeneration rate) |D| is large, i.e., the spatial scale of the solution is small. Following the general idea of an asymptotic solution for dynamo waves (e.g., Kuzanyan & Sokoloff 1995), we search for a solution in the form of a power series with respect to the small parameter |D|–1/3(short wavelength scale). This solution is of the order of magnitude of exp(i|D|1/3S), where S is a scalar function of position.


1999 ◽  
Vol 4 (1) ◽  
pp. 6-7
Author(s):  
James J. Mangraviti

Abstract The accurate measurement of hip motion is critical when one rates impairments of this joint, makes an initial diagnosis, assesses progression over time, and evaluates treatment outcome. The hip permits all motions typical of a ball-and-socket joint. The hip sacrifices some motion but gains stability and strength. Figures 52 to 54 in AMA Guides to the Evaluation of Permanent Impairment (AMA Guides), Fourth Edition, illustrate techniques for measuring hip flexion, loss of extension, abduction, adduction, and external and internal rotation. Figure 53 in the AMA Guides, Fourth Edition, illustrates neutral, abducted, and adducted positions of the hip and proper alignment of the goniometer arms, and Figure 52 illustrates use of a goniometer to measure flexion of the right hip. In terms of impairment rating, hip extension (at least any beyond neutral) is irrelevant, and the AMA Guides contains no figures describing its measurement. Figure 54, Measuring Internal and External Hip Rotation, demonstrates proper positioning and measurement techniques for rotary movements of this joint. The difference between measured and actual hip rotation probably is minimal and is irrelevant for impairment rating. The normal internal rotation varies from 30° to 40°, and the external rotation ranges from 40° to 60°.


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