Selective Synthesis of Various Photofunctional Multinuclear Complexes Using a Combination of the Mizoroki–Heck Reaction and the Homo-coupling Reaction

2021 ◽  
pp. 33-57
Author(s):  
Yasuomi Yamazaki
Keyword(s):  
Heck Reaction ◽  
Coupling Reaction ◽  
Selective Synthesis ◽  
Multinuclear Complexes

scholarly journals Synthesis of novel photofunctional multinuclear complexes using a coupling reaction

2015 ◽  
Vol 44 (25) ◽  
pp. 11626-11635 ◽  
Author(s):  
Yasuomi Yamazaki ◽  
Tatsuki Morimoto ◽  
Osamu Ishitani
Keyword(s):  
Heck Reaction ◽  
Coupling Reaction ◽  
Mononuclear Complexes ◽  
Multinuclear Complexes

Various photofunctional mononuclear complexes could be integrated into hetero-multinuclear complexes using the Mizoroki–Heck reaction.

Visible light-driven photocatalytic Heck reaction over carbon nanocoil supported Pd nanoparticles

2016 ◽  
Vol 6 (21) ◽  
pp. 7738-7743 ◽  
Author(s):  
Xiao-Wei Guo ◽  
Cai-Hong Hao ◽  
Cheng-Yu Wang ◽  
Sarina Sarina ◽  
Xiao-Ning Guo ◽  
...  
Keyword(s):  
Visible Light ◽  
Heck Reaction ◽  
Coupling Reaction ◽  
Pd Nanoparticles ◽  
Aryl Halides ◽  
Pd Nanoparticle ◽  
Visible Light Driven ◽  
Nanoparticle System ◽  
Supported Pd

This paper presents a carbon nanocoil supported Pd nanoparticle system (Pd/CNCs) as a photocatalyst for coupling reaction of aryl halides and alkenes (Heck reaction) at 40 °C.

ChemInform Abstract: Selective Synthesis of Partially Protected Nonsymmetric Biphenols by Reagent- and Metal-Free Anodic Cross-Coupling Reaction.

ChemInform ◽  
2016 ◽  
Vol 47 (52) ◽  
Author(s):  
Anton Wiebe ◽  
Dieter Schollmeyer ◽  
Katrin M. Dyballa ◽  
Robert Franke ◽  
Siegfried R. Waldvogel
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Selective Synthesis ◽  
Metal Free ◽  
Cross Coupling Reaction

Palladium Nanoparticles Anchored on Magnesium Organosilicate: An Effective and Selective Catalyst for the Heck Reaction

Synthesis ◽  
2020 ◽  
Author(s):  
Nelson Luís C. Domingues ◽  
Beatriz F. dos Santos ◽  
Beatriz A. L. da Silva ◽  
Aline R. de Oliveira ◽  
Maria H. Sarragiotto ◽  
...  
Keyword(s):  
Heck Reaction ◽  
Palladium Nanoparticles ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Amorphous Solid ◽  
Selective Catalyst ◽  
Cross Coupling Reaction ◽  
Efficient Route ◽  
High Yields ◽  
Short Time

AbstractA new and effective palladium catalyst supported on a magnesium organosilicate for application in the Heck reaction is presented. A group of compounds comprising 22 examples were synthesized in moderate to high yields (up to 99%) within a short time. The palladium supported on magnesium organosilicate catalyst was characterized as an amorphous solid by SEM, containing around 33% of palladium inside the solid, and even with this low quantity of palladium, the catalyst was very efficient in the Heck reaction. Besides, based on the Scherrer equation, the crystallite size of the synthesized palladium nanoparticles was ultrasmall (around 1.3 nm). This strategy is a simple and efficient route for the formation of C–C bonds via the Heck cross-coupling reaction.

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