Tertiary arsine ligands for Stille coupling reaction

Stille coupling reaction is one of the most important coupling reactions. It is well known that triphenylarsine ligand can accelerate the reaction rate of Stille coupling. However, other arsine ligands...

A regioselective double Stille coupling reaction of bicyclic stannolanes

A regioselective double Stille coupling reaction was explored using bicyclic stannolanes that were easily prepared from the radical cascade reaction of β-amino-α-methylene esters.

Highly selective palladium-catalyzed Stille coupling reaction toward chlorine-containing NIR electroluminescent polymers

Chlorine-containing conjugated polymers were obtained by the optimized Stille coupling reaction; non-doped PLEDs of the polymers exhibited NIR emission.

Synthesis, photophysics and electrochemical properties of 1,1′-(2,2′-bithiophene-5,5′-diyl)bis(cycloalkeno[c]pyridine) as a result of the Diels–Alder reaction of 3-(2-thienyl)-1,2,4-triazine

Fused pyridine 2,2′-bithiophenes were prepared via [4+2] cycloaddition based on 3-(2-thienyl)-1,2,4-triazine, which was obtained by the Stille coupling reaction.

Investigation of the structure–property relationship of thiadiazoloquinoxaline-based copolymer semiconductors via molecular engineering

Six thiadiazoloquinoxaline (TQ) based copolymers (P1–P6) have been synthesized using Stille coupling reaction upon varying donor moieties, substitution positions and architectures of polymer side chains.