Mixed metal complexes in solution. Part 4. Formation and stability of heterobinuclear complexes of cadmium(II)-citrate with some bivalent metal ions in aqueous solution

1985 ◽  
Vol 10 (1) ◽  
pp. 11-14 ◽  
Author(s):  
Paola Amico ◽  
Pier Giuseppe Daniele ◽  
Giorgio Ostacoli ◽  
Guiseppe Arena ◽  
Enrico Rizzarelli ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Metal Ions ◽  
Metal Complexes ◽  
Bivalent Metal ◽  
Mixed Metal ◽  
Bivalent Metal Ions ◽  
Mixed Metal Complexes

Mixed-metal complexes in solution. 3. Thermodynamic study of heterobinuclear copper(II)-L-histidine and -histamine complexes in aqueous solution

1981 ◽  
Vol 20 (3) ◽  
pp. 772-777 ◽  
Author(s):  
Paola. Amico ◽  
Giuseppe. Arena ◽  
Pier G. Daniele ◽  
Giorgio. Ostacoli ◽  
Enrico. Rizzarelli ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Metal Complexes ◽  
Thermodynamic Study ◽  
Mixed Metal ◽  
Mixed Metal Complexes

Mixed metal complexes in solution. Part II. Potentiometric study of heterobinuclear metal(II)citrate complexes in aqueous solution

1980 ◽  
Vol 44 ◽  
pp. L219-L221 ◽  
Author(s):  
Paola Amico ◽  
Pier Giuseppe Daniele ◽  
Giorgio Ostacoli ◽  
Giuseppe Arena ◽  
Enrico Rizzarelli ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Metal Complexes ◽  
Potentiometric Study ◽  
Mixed Metal ◽  
Mixed Metal Complexes

scholarly journals Synthesis and characterization of novel four heterodimetallic mixed metal complexes of 2,6-pyridinedicarboxylic acid

2020 ◽  
Vol 34 (2) ◽  
pp. 313-321
Author(s):  
H. İlkimen ◽  
R. S. Canlıdinç
Keyword(s):  
Metal Ions ◽  
Metal Complexes ◽  
Magnetic Measurement ◽  
Thermal Analyses ◽  
Mixed Metal ◽  
Carboxylate Oxygen ◽  
Pyridinedicarboxylic Acid ◽  
Metal Metal ◽  
Mixed Metal Complexes

Four novel hetero dimetallic mixed metal complexes of 2,6-pyridinedicarboxylic acid       (H2dipic), [Ni(H2O)5Co(dipic)2] (1), [Co(H2O)5Co(dipic)2][Ni(H2O)5Ni(dipic)2][Co(dipic)(H2O)3] (2), [Cu(H2O)5Ni(dipic)2]2[Co(dipic)(H2O)] (3) and [Ni(H2O)5Cu(dipic)2]2[Co(dipic)(H2O)] (4) have been prepared and characterized by elemental, AAS, spectral (IR and UV-Vis), and thermal analyses, as well as by using magnetic measurement and molar conductivity techniques. The results indicate that metal ions coordinate with 2,6-pyridinedicarboxylate ions (dipic2-) nitrogen atoms and carboxylate oxygen atoms of ligands. The mole ratio of dipic2- and metal ions in the complexes have been determined to be 2:2 (Co, Ni) for 1, 5:5 (3Co, 2Ni) for 2, 5:5 (Co, 2Ni and 2Cu) for 3 and 5:5 (Co, 2Ni and 2Cu) for 4 according to the results of elemental analysis. The structures of 1-4 might be proposed as octahedral ([Cu(dipic)(H2O)] unit for 2 square plane) according to results of spectroscopic analysis. The TG and DTA properties of compounds have been studied.                     KEY WORDS: 2,6-Pyridinedicarboxylic acid, Mixed metal, Metal complex   Bull. Chem. Soc. Ethiop. 2020, 34(2), 313-321 DOI: https://dx.doi.org/10.4314/bcse.v34i2.9

Ligand(s)-to-metal charge transfer as a factor controlling the equilibrium constants of late first-row transition metal complexes: revealing the Irving–Williams thermodynamical series

2015 ◽  
Vol 17 (2) ◽  
pp. 805-811 ◽  
Author(s):  
Pradeep R. Varadwaj ◽  
Arpita Varadwaj ◽  
Bih-Yaw Jin
Keyword(s):  
Charge Transfer ◽  
Transition Metal ◽  
Metal Ions ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Equilibrium Constants ◽  
Bivalent Metal ◽  
Metal Charge ◽  
Bivalent Metal Ions ◽  
Metal Charge Transfer

Ligand(s)-to-metal charge transfer obtained from QTAIM charges unravel the Irving–William series for the equilibrium constants of late first-row bivalent metal ions.

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