Proposed scheme for reconstruction of reactor section of 1A/1M cat cracker

1995 ◽  
Vol 31 (1) ◽  
pp. 3-7
Author(s):  
A. F. Babikov ◽  
B. Z. Solyar ◽  
L. Sh. Glazov ◽  
R. V. Basov ◽  
T. Kh. Melik-Akhnazarov ◽  
...  
Keyword(s):  

2019 ◽  
Author(s):  
Merlin Kleoff ◽  
Johannes Schwan ◽  
Lisa Boeser ◽  
Bence Hartmayer ◽  
Mathias Christmann ◽  
...  

A scalable access to functionalized 1,1’- and 1,2-ferrocenyl azides has been realized in flow. By halogen‒lithium exchange of ferrocenyl halides and subsequent reaction with tosyl azide, a variety of functionalized ferrocenyl azides was obtained in high yields. To allow a scalable preparation of these potentially explosive compounds, an efficient flow protocol was developed accelerating the reaction time to minutes and circumventing accumulation of potentially hazardous intermediates. Switching from homogeneous to triphasic flow amidst process was key for handling a heterogeneous reaction mixture formed after a heated reactor section. The corresponding and synthetically versatile ferrocenyl amines were then prepared by a reliable reduction process.



1988 ◽  
Vol 24 (3) ◽  
pp. 112-117
Author(s):  
V. A. Stankevich ◽  
K. O. Shakhovskii ◽  
N. L. Yushchenko ◽  
A. Ya. Chernyak ◽  
R. V. Basov ◽  
...  


1988 ◽  
Vol 25 (2) ◽  
pp. 57-62
Author(s):  
G. E. Lazebnik ◽  
L. A. Berdichevskii ◽  
A. A. Smirnov ◽  
N. S. Sokolov


2005 ◽  
Vol 44 (16) ◽  
pp. 6067-6074 ◽  
Author(s):  
Xuqi Song ◽  
John R. Grace ◽  
Hsiaotao Bi ◽  
C. Jim Lim ◽  
Edward Chan ◽  
...  
Keyword(s):  




2019 ◽  
Author(s):  
Merlin Kleoff ◽  
Johannes Schwan ◽  
Lisa Boeser ◽  
Bence Hartmayer ◽  
Mathias Christmann ◽  
...  

A scalable access to functionalized 1,1’- and 1,2-ferrocenyl azides has been realized in flow. By halogen‒lithium exchange of ferrocenyl halides and subsequent reaction with tosyl azide, a variety of functionalized ferrocenyl azides was obtained in high yields. To allow a scalable preparation of these potentially explosive compounds, an efficient flow protocol was developed accelerating the reaction time to minutes and circumventing accumulation of potentially hazardous intermediates. Switching from homogeneous to triphasic flow amidst process was key for handling a heterogeneous reaction mixture formed after a heated reactor section. The corresponding and synthetically versatile ferrocenyl amines were then prepared by a reliable reduction process.



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