On the denitration of the trinitromethyl group in acid medium

1966 ◽  
Vol 15 (10) ◽  
pp. 1778-1779 ◽  
Author(s):  
V. A. Tartakovskii ◽  
I. E. Chlenov ◽  
S. S. Novikov
Keyword(s):  
Acid Medium ◽  
Trinitromethyl Group

Kinetics and Mechanism of Oxidation of Paracetamol by Thallic Perchlorate in Acid Medium

2015 ◽  
Vol 4 (3) ◽  
pp. 302-309 ◽  
Author(s):  
Deepmala Pareek ◽  
Riya Sailani ◽  
Vinita Gupta ◽  
Chandra Khandelwal ◽  
Prem Sharma
Keyword(s):  
Acid Medium ◽  
Kinetics And Mechanism ◽  
Mechanism Of Oxidation

CORROSION INHIBITION OF ZINC IN HYDROCHLORIC ACID MEDIUM USING UREA INHIBITOR

2007 ◽  
Vol 10 (2) ◽  
pp. 31-38 ◽  
Author(s):  
Khulood AL-Saadie ◽  
◽  
Nadia Abdul Karime ◽  
Israa M Al-Mousawi ◽  
◽  
...  
Keyword(s):  
Hydrochloric Acid ◽  
Acid Medium ◽  
Corrosion Inhibition ◽  
Hydrochloric Acid Medium

Oxidation mechanism of carcinogenic bis-azo dyestuff Trypan Blue

1982 ◽  
Vol 47 (10) ◽  
pp. 2746-2748 ◽  
Author(s):  
Miroslav Matrka ◽  
Jana Pípalová
Keyword(s):  
Acid Medium ◽  
Quantitative Evaluation ◽  
Oxidation Product ◽  
Trypan Blue ◽  
Oxidation Mechanism ◽  
Azo Coupling ◽  
Arenediazonium Salt

Oxidation of Trypan Blue with cerium(IV) ion in acid medium gives arenediazonium cation similar to the oxidation product of N,N-dimethyl-4-aminoazobenzene. Quantitative evaluation of the arenediazonium salt formed has been carried out spectrophotometrically after previous C-azo coupling with 2-naphthol.

Solvolysis kinetics and mechanism of substituted 3-acetyl-1,3-diphenyltriazenes in acid medium; Kinetic acidity function

1987 ◽  
Vol 52 (9) ◽  
pp. 2212-2216
Author(s):  
Oldřich Pytela ◽  
Martin Kaska ◽  
Miroslav Ludwig ◽  
Miroslav Večeřa
Keyword(s):  
Acid Medium ◽  
Sulphuric Acid ◽  
Rate Constants ◽  
Decomposition Kinetics ◽  
Acidity Function ◽  
Hammett Equation ◽  
Kinetic Acidity ◽  
Reaction Constant ◽  
Acid Catalyzed ◽  
Catalytic Rate

The decomposition kinetics has been measured of fourteen 3-acetyl-1,3-bis(subst. phenyl)triazenes in 40% (v/v) ethanol and sulphuric acid. The kinetic acidity function and catalytic rate constants have been determined from the rate constants observed. Mechanism has been suggested for the general acid-catalyzed solvolysis from comparison of the course of the kinetic acidity function and H0 function and from the reaction constant of the Hammett equation.

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