Use of the method of moments for the determination of the coefficients of internal diffusion in the case of adsorbents with a bidispersed porous structure and linear adsorption isotherms

1974 ◽  
Vol 23 (6) ◽  
pp. 1178-1181 ◽  
Author(s):  
A. M. Voloshchuk ◽  
P. P. Zolotarev ◽  
V. I. Ulin
Keyword(s):  
Porous Structure ◽  
Adsorption Isotherms ◽  
Method Of Moments ◽  
Internal Diffusion

Determination of the degree of adsorption and the heat of adsorption for 1-butylamine and ammonia on NaHY zeolites

1984 ◽  
Vol 49 (12) ◽  
pp. 2739-2743 ◽  
Author(s):  
Miloslav Křivánek ◽  
Pavel Jírů
Keyword(s):  
Lewis Acid ◽  
Adsorption Isotherms ◽  
Heat Of Adsorption ◽  
Brønsted And Lewis Acid

The degree and heat of adsorption of 1-butylamine and ammonia were measured on samples of NaHY zeolites activated at 400-600°C. The adsorption isotherms and calorimetric curves were compared for the two bases, and the amount of Bronsted and Lewis acid centres was determined from the calorimetric curves.

scholarly journals Computer Analysis of the Porous Structure of Activated Carbons Derived from Various Biomass Materials by Chemical Activation

Materials ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4121
Author(s):  
Mirosław Kwiatkowski ◽  
Elżbieta Broniek
Keyword(s):  
Porous Structure ◽  
Adsorption Isotherms ◽  
Computer Analysis ◽  
Activated Carbons ◽  
Chemical Activation ◽  
Adsorbed Layer ◽  
Dry Mass ◽  
Mass Ratio ◽  
Adsorption Volume ◽  
Homogeneous Surface

In this study, the preparation of activated carbons from various materials of biomass origin by activation with potassium hydroxide and a comprehensive computer analysis of their porous structure and adsorption properties based on benzene (C6H6) adsorption isotherms were carried out. In particular, the influence of the mass ratio of the activator’s dry mass to the char mass on the formation of the microporous structure of the obtained activated carbons was analysed. The summary of the analyses carried out based on benzene adsorption isotherms begged the conclusion that activated carbon with a maximum adsorption volume in the first adsorbed layer and homogeneous surface can be obtained from ebony wood at a mass ratio of the activator to the char of R = 3. The obtained results confirmed the superiority of the new numerical-clustering-based adsorption analysis (LBET) method over simple methods of porous structure analysis, such as the Brunauer–Emmett–Teller (BET) and Dubinin–Raduskevich (DR) methods. The LBET method is particularly useful in the evaluation of the influence of the methods and conditions of production of activated carbons on the formation of their porous structure. This method, together with an appropriate economic analysis, can help in the precise selection of methods and conditions for the process of obtaining activated carbons at specific manufacturing costs, and thus makes it possible to obtain materials that can successfully compete with those of other technologies used in industrial practice and everyday life.

LINURON ADSORPTION AND THE DEGREE OF DECOMPOSITION OF PEATS AS MEASURED BY RUBBED FIBRE CONTENT AND PYROPHOSPHATE INDEX

1976 ◽  
Vol 56 (2) ◽  
pp. 105-109 ◽  
Author(s):  
H. MORITA
Keyword(s):  
Adsorption Isotherms ◽  
Fibre Content ◽  
Extraction Technique ◽  
Adsorption Coefficient ◽  
Column Extraction

Determination of the Freundlich adsorption isotherms for linuron with some peats showed that the adsorption coefficient, K, is closely related to the degree of decomposition as measured by the rubbed fibre content and the pyrophosphate index. The K values indicate that adsorption increases with decomposition. The analyses required for the determination of K were facilitated by the use of a column extraction technique.

Determination of adsorption isotherms and solute activities from spreading pressure-surface charge data

1977 ◽  
Vol 62 (3) ◽  
pp. 454-460 ◽  
Author(s):  
Sherril D Christian ◽  
Glenn Dryhurst ◽  
Viktor Brabec ◽  
James G Baker
Keyword(s):  
Surface Charge ◽  
Adsorption Isotherms ◽  
Spreading Pressure ◽  
Pressure Surface
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