Simultaneous radiometric determination of uranium and thorium in sulfuric acid solutions

1972 ◽  
Vol 31 (6) ◽  
pp. 1425-1427 ◽  
Author(s):  
V. V. Anosov ◽  
N. I. Gavrilov ◽  
T. P. Smelkova



1955 ◽  
Vol 27 (3) ◽  
pp. 455-457 ◽  
Author(s):  
E. G. Cogbill ◽  
J. C. White ◽  
C. D. Susano


1990 ◽  
Vol 68 (10) ◽  
pp. 1653-1656 ◽  
Author(s):  
Y. Chiang ◽  
A. J. Kresge ◽  
R. A. More O'ferrall ◽  
B. A. Murray ◽  
N. P. Schepp ◽  
...  

Rates of ketonization of the enol of acetophenone, generated by flash photolytic photohydration of phenylacetylene, were measured in aqueous sulfuric and perchloric acid solutions over the concentration range 1–50 wt.% acid; rates of enolization of acetophenone, monitored by bromine scavenging, were also measured in aqueous perchloric acid solutions over the same concentration range. The results suggest that the curvature observed in a previous X acidity function correlation of the rate of enolization in sulfuric acid solutions was an artifact produced by insufficiently efficient scavenging, and that introduction of the activity of water in the correlating expression, used previously to eliminate the curvature and believed to reflect covalent involvement of water in the enolization reaction, is unnecessary. The present results also show that the keto–enol equilibrium constant for acetophenone decreases with increasing acidity in these concentrated sulfuric and perchloric acid solutions. Key words: acetophenone, enolization, ketonization, keto–enol equilibrium, concentrated acid solutions.



1983 ◽  
Vol 51 (3) ◽  
pp. 302-309 ◽  
Author(s):  
Yasuhiro AWAKURA ◽  
Tatsuhiko MICHIMOTO ◽  
Yasushi TAKESHIMA ◽  
Hiroshi MAJIMA




2012 ◽  
Vol 45 (6) ◽  
pp. 1198-1207 ◽  
Author(s):  
Helen E. Maynard-Casely ◽  
Helen E. A. Brand ◽  
Kia S. Wallwork

Synchrotron X-ray powder diffraction has been used to structurally characterize crystallization products from 37.8 and 40.5 wt% aqueous sulfuric acid solutions. It is confirmed that, despite speculation in the literature, the structure that predominately crystallized from these solutions is sulfuric acid octahydrate (SAO). The existence of an uncharacterized phase is also noted. It was found that existing models proposed for the crystal structure of SAO did not satisfactorily fit to the data acquired here, and hence a new structure solution was sought. It is reported here that the structure of SAO is contained within a unit cell withI2 symmetry witha= 7.44247 (11),b= 7.4450 (1),c= 26.1168 (3) Å, β = 125.0428 (7)°,V= 1184.78 (3) Å3at 80 K. Data were collected at temperatures between 80 and 198 K, which enabled determination of the thermal expansion of SAO.



Author(s):  
Ya.G. Avdeev ◽  
◽  
Yu.B. Makarychev ◽  
D.S. Kuznetsov ◽  
L.P. Kazanskii ◽  
...  




Sign in / Sign up

Export Citation Format

Share Document