Experimental and theoretical studies of anions of transition-metal chelate complexes in alkylation reactions at a metal atom

1999 ◽  
Vol 48 (1) ◽  
pp. 71-78 ◽  
Author(s):  
K. P. Butin ◽  
R. D. Rakhimov ◽  
I. G. Il'ina
Molecules ◽  
2020 ◽  
Vol 25 (21) ◽  
pp. 4943 ◽  
Author(s):  
Lili Zhao ◽  
Chaoqun Chai ◽  
Wolfgang Petz ◽  
Gernot Frenking

This review summarizes experimental and theoretical studies of transition metal complexes with two types of novel metal-carbon bonds. One type features complexes with carbones CL2 as ligands, where the carbon(0) atom has two electron lone pairs which engage in double (σ and π) donation to the metal atom [M]⇇CL2. The second part of this review reports complexes which have a neutral carbon atom C as ligand. Carbido complexes with naked carbon atoms may be considered as endpoint of the series [M]-CR3 → [M]-CR2 → [M]-CR → [M]-C. This review includes some work on uranium and cerium complexes, but it does not present a complete coverage of actinide and lanthanide complexes with carbone or carbide ligands.


1993 ◽  
Vol 3 (3) ◽  
pp. 102-104 ◽  
Author(s):  
Vladimir I. Minkin ◽  
Nikolai V. Volbushko ◽  
Mikhail S. Korobov ◽  
Leonid E. Nivorozhkin

2019 ◽  
Vol 43 (42) ◽  
pp. 16621-16628 ◽  
Author(s):  
Prasanta Bandyopadhyay ◽  
Rajkumar Jana ◽  
Kalishankar Bhattacharyya ◽  
Oleg I. Lebedev ◽  
Uma Dutta ◽  
...  

Schematic diagram of metal oxide–BTT interaction and the associated changes in experimental UV-Vis spectra. BTT adsorbed α-Fe2O3 is represented by red spectra, while green spectra represent BTT adsorbed NiO. Black spectra represent pure BTT spectra.


Polyhedron ◽  
2018 ◽  
Vol 151 ◽  
pp. 74-81 ◽  
Author(s):  
Inna M. Grigorieva ◽  
Tatiyana V. Serebryanskaya ◽  
Yuri V. Grigoriev ◽  
Alexander S. Lyakhov ◽  
Ludmila S. Ivashkevich ◽  
...  

1987 ◽  
Vol 26 (13) ◽  
pp. 2171-2176 ◽  
Author(s):  
Martin M. Finnegan ◽  
Tammy G. Lutz ◽  
William O. Nelson ◽  
Alexis Smith ◽  
Chris Orvig

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