Thermodynamic activity of antimony at dilute solutions in carbon-saturated liquid iron

1993 ◽  
Vol 24 (6) ◽  
pp. 963-973 ◽  
Author(s):  
C. L. Nassaralla ◽  
E. T. Turkdogan
Keyword(s):  
Liquid Iron ◽  
Thermodynamic Activity ◽  
Saturated Liquid ◽  
Dilute Solutions

Interaction Parameter e OC for Carbon-saturated Liquid Iron between 1623 and 1723 K

2010 ◽  
Vol 81 (5) ◽  
pp. 333-336
Author(s):  
Y. Kashiwaya ◽  
M. Hasegawa ◽  
H. Niitani ◽  
T. Kakinuma ◽  
M. Iwase
Keyword(s):  
Interaction Parameter ◽  
Liquid Iron ◽  
Saturated Liquid

Rate of molybdenum solution in carbon-saturated liquid iron

1972 ◽  
Vol 3 (9) ◽  
pp. 2337-2342 ◽  
Author(s):  
Richard B. Gundlach ◽  
Robert D. Pehlke
Keyword(s):  
Liquid Iron ◽  
Saturated Liquid

Thermodynamic Properties of CS and Solutions of Sulfur in Carbon-Saturated Liquid Iron

JOM ◽  
1957 ◽  
Vol 9 (5) ◽  
pp. 690-694 ◽  
Author(s):  
C. J. B. Fincham ◽  
R. A. Bergman
Keyword(s):  
Thermodynamic Properties ◽  
Liquid Iron ◽  
Saturated Liquid

scholarly journals Interaction parameters of oxygen and deoxidants in liquid iron

2016 ◽  
Vol 52 (1) ◽  
pp. 41-46 ◽  
Author(s):  
e Costa
Keyword(s):  
Liquid Iron ◽  
Atomic Number ◽  
Thermodynamic Modeling ◽  
Calphad Method ◽  
Interaction Parameters ◽  
Heats Of Formation ◽  
Dilute Solution ◽  
Dilute Solutions ◽  
Interaction Coefficients ◽  
Computational Tools

During decades before the evolution of more powerful computational tools, simplified formalisms such as the Wagner dilute solution formalism, have been successfully used in the study of deoxidation reactions of steel. This formalism relies on the introduction of interaction coefficients to account from deviations from Henry?s Law. With the evolution of thermodynamic modeling and of the CALPHAD method, the fact that thermodynamic descriptions using these parameters were derived to be used at relatively dilute solution has been sometimes overlooked and the formalism has been criticized for deviating from reality in non-dilute solutions. In this work, it is shown that the interaction parameters used in this formalism correlate with properties of the solutes and of the solvent. The work focuses on the interactions in systems Fe-M-O, where M is a deoxidant. Correlations between interaction coefficients and heats of formation of the corresponding oxides and with the atomic number of the deoxidants are demonstrated. This not only helps supporting the physicochemical soundness of the formalism but also provides a way of checking the consistency of data presented in this formalism.

scholarly journals Copper Distribution between FeS-Na2S Flux and Carbon Saturated Liquid Iron

1991 ◽  
Vol 77 (4) ◽  
pp. 504-511 ◽  
Author(s):  
Chao WANG ◽  
Tetsuya NAGASAKA ◽  
Mitsutaka HINO ◽  
Shiro BAN-YA
Keyword(s):  
Liquid Iron ◽  
Saturated Liquid ◽  
Copper Distribution

scholarly journals Fabrication of ZrO2(MgO)/CaAl2O4+CaAl4O7 Bilayer Structure Used for Sulfur Sensor by Laser Cladding

2019 ◽  
Vol 9 (6) ◽  
pp. 1036
Author(s):  
Tianpeng Wen ◽  
Jingkun Yu ◽  
Endong Jin ◽  
Lei Yuan ◽  
Yuting Zhou ◽  
...  
Keyword(s):  
Phase Composition ◽  
Ionic Conductivity ◽  
Solid Electrolyte ◽  
Liquid Iron ◽  
Laser Cladding ◽  
Bilayer Structure ◽  
Saturated Liquid ◽  
Stabilized Zirconia ◽  
Sulfur Determination ◽  
The Stability

The ZrO2(MgO)/CaAl2O4+CaAl4O7 bilayer structure used for sulfur sensor was fabricated by the laser powder cladding (LPC) method using the MgO partially stabilized zirconia (2.7 wt% MgO-PSZ) as the substrate and the CaAl2O4 + CaAl4O7 composites as the coating material. The microstructure, phase composition and ionic conductivity of this bilayer structure were investigated for better application in the sulfur determination. The results indicated that the structure of the coating was dense and well-distributed with a thickness of 100 μm. The ionic conductivity of the ZrO2(MgO)/CaAl2O4+CaAl4O7 bilayer structure was up to 2.06 × 10−3 S·cm−1 at 850 °C that met the required ionic conductivity of ionic conductor for solid electrolyte sulfur sensor. Furthermore, the sulfur sensor Mo|Cr+Cr2O3| ZrO2(MgO)| CaAl2O4+CaAl4O7|[S]Fe| Mo was assembled used this bilayer structure and tested in carbon-saturated liquid iron at 1773 K and 1823 K. The stability and reproducibility of the sulfur sensor were satisfactory and could be used for sulfur determination in the liquid iron.

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