Abstract
The studied gabbroic nodules occurring in the Petrazza pyroclastic rocks
consist mainly of plagioclase (An95–87), olivine
(Fo83-73) and clinopyroxene (Mg# 90–77), with subordinate
opaques (Ti-magnetite) and amphibole (Mg-hastingsite), which constitute the
cumulate minerals. Interstitial material has a relatively high, but variable,
degree of vesicularity and consists of variable amounts of glass and quenched
crystals of plagioclase (An71–55), amphibole, clinopyroxene
and rare biotite, olivine and opaques. Silicate melt inclusions are abundant in
the cumulate minerals, but complete homogenization to melt has been observed only
in the inclusions occurring in clinopyroxene, where the temperatures of
homogenization vary from 1134 to 1190°C. Microthermometric investigations of fluid
inclusions and of the shrinkage bubble of the melt inclusions suggest that the
magma contained CO2. The apparent scarcity of
H2O indicates that this component was strongly partitioned
into the magma at the time of crystallization of the investigated minerals; this
is further supported by the occurrence of (1) daughter biotite- and
amphibole-bearing inclusions which show that the H2O activity
in the magma was sufficiently high to allow their crystallization, and (2) calcic
plagioclase (An95–87) which can be crystallized from a
high-alumina basaltic magma at pressure ≤2 kbar, temperatures in the range
1050–1100°C and in the presence of 3–4 wt.% of water (MELTS software
simulations).
The composition of the melt inclusions suggests that the hosting plagioclase,
olivine and clinopyroxene crystallized from slightly different batches of magma.
The S content in the melt inclusions of clinopyroxene and olivine is high (up to
0.41 wt.%). The presence of Fe-Cu(-Ni)-rich blebs of sulphide in plagioclase,
olivine, amphibole, and locally in the melt inclusions too, further supports the
important role of sulphur in the primitive magmas of the investigated gabbros.
Small differences in redox conditions or in the Fe content of the melts favoured S
mobilization as sulphide.