Temporal Evolution of Cooling by Natural Convection in an Enclosed Magma Chamber

This research numerically studies the transient cooling of partially liquid magma by natural convection in an enclosed magma chamber. The mathematical model is based on the conservation laws for momentum, energy and mass for a non-Newtonian and incompressible fluid that may be modeled by the power law and the Oberbeck–Boussinesq equations (for basaltic magma) and solved with the finite volume method (FVM). The results of the programmed algorithm are compared with those in the literature for a non-Newtonian fluid with high apparent viscosity (10–200 Pa s) and Prandtl (Pr = 4 × 104) and Rayleigh (Ra = 1 × 106) numbers yielding a low relative error of 0.11. The times for cooling the center of the chamber from 1498 to 1448 K are 40 ky (kilo years), 37 and 28 ky for rectangular, hybrid and quasi-elliptical shapes, respectively. Results show that for the cases studied, natural convection moved the magma but had no influence on the isotherms; therefore the main mechanism of cooling is conduction. When a basaltic magma intrudes a chamber with rhyolitic magma in our model, natural convection is not sufficient to effectively mix the two magmas to produce an intermediate SiO2 composition.

“ORE MAGMA”. WHAT IS IT FROM THE STANDPOINT OF THE GRANITE ORE-MAGMATIC SYSTEM?

The concept of “ore magma” remains an obscure hypothesis in ore formation. The article considers the process of natural overgrowth of trivial primary basaltic magma into an ore-bearing granite melting and further into the ore-forming “ore magma” as the concentration of volatile and ore components. The dark side of the problem lies in the fact that during the ore formation the “ore magma” liquates into contrasting phases and leaves practically no traces of itself (with rare exceptions). But the concept of the ore magma has received a logical scientific justification from the standpoint of ore-magmatic systems.

Vilyui-Markha interfluve of Yakutia: a region prospective for Cu-Ni-PGM mineralization

Materials are discussed on geologically similar structure of Norilsk ore district (NOD) and Vilyui-Markha interstream area (VMIA), which implies the latter prospects for Cu-Ni-PGM mineralization. Data is provided on Cu-Ni-Co-Zn mineral occurrences within Ygyattinsky diamondiferous region centered on VMIA. Geological similarities of NOD and VMIA are summarized below. Both regions are located in Mesozoic tectonomagmatic activation domain at the edge of large troughs: NOD is localized in the Siberian platform foredeep, and VMIA lies at Vilyui syneclise margin. NOD deposits are hosted by centroclines of large brachysynclines at slopes of Pyasinskoye dome. Within VMIA, prospects are located at Syuldyukarskoye dome slopes in margibal parts of large troughs. NOD and VMIA comprise Paleozoic marl-carbonate strata overlain by carbonaceous Carboniferous-Permian overburden, which could be assimilated by basaltic magma in Mesozoic contributing to its ore differentiation. Norilsk-Kharaelakh ore-bearing intrusion in VMIA appears to be similar to Kholomolokh sulfide-rich intrusion with its inferred extensive ore-bearing sills. They have similar composition and structure including presence of pegmatites. Ore-controlling Norilsk-Kharaelakh fault is believed to be simi- lar to Khatyryk-Kholomolokh fault, which was traced for 24 km by drilling and is one of sutures within deep-seated kimberlite-controlling Vilyui-Markha zone. This fault’s impact zone host concentrated geochemical anomalies and Cu-Ni-Co-Zn-Pt-Au-Ag Khomustakh occurrence. Based on this, Norilsk-type Cu-Ni prospects ranked as a potential ore cluster and three ore fields were identified

Thermodynamic limits for assimilation of silicate crust in primitive magmas

Some geochemical models for basaltic and more primitive rocks suggest that their parental magmas have assimilated tens of weight percent of crustal silicate wall rock. But what are the thermodynamic limits for assimilation in primitive magmas? We pursue this question quantitatively using a freely available thermodynamic tool for phase equilibria modeling of open magmatic systems—the Magma Chamber Simulator (https://mcs.geol.ucsb.edu)—and focus on modeling assimilation of wall-rock partial melts, which is thermodynamically more efficient compared to bulk assimilation of stoped wall-rock blocks in primitive igneous systems. In the simulations, diverse komatiitic, picritic, and basaltic parental magmas assimilate progressive partial melts of preheated average lower, middle, and upper crust in amounts allowed by thermodynamics. Our results indicate that it is difficult for any subalkaline primitive magma to assimilate more than 20–30 wt% of upper or middle crust before evolving to compositions with higher SiO2 than a basaltic magma (52 wt%). On the other hand, typical komatiitic magmas have thermodynamic potential to assimilate as much as their own mass (59–102 wt%) of lower crust and retain a basaltic composition. The compositions of the parental melt and the assimilant heavily influence both how much assimilation is energetically possible in primitive magmas and the final magma composition given typical temperatures. These findings have important implications for the role of assimilation in the generation and evolution of, e.g., ultramafic to mafic trans-Moho magmatic systems, siliceous high-Mg basalts, and massif-type anorthosites.

Petrology and Geochemistry of Rocks of Ishiagu and Environs Southeastern Nigeria Using Ed-Xrf Method

Geochemistry of rocks of Ishiagu area was carried out using Energy Dispersive X-Ray fluorescence (ED-XRF) method. Twelve samples were analyzed and their geochemical properties determined using Excel-Software. Geological mapping reveals that basalts, dolerites and diorites emplaced in shale and mudrock country hosts are the main lithological units occurring in the area. They have silica content of 40.4–49.2wt.%, indicating they are basic-ultrabasic in character. The dolerite and diorite contain average plagioclase (An70-17.4vol.%), hematite 26.29vol.%, showing enrichment in ferromagnesian minerals and depletion in quartz. The Na2O and K2O averaged 1.22wt.% and 1.46wt.% respectively, indicating depletion in alkali, thus corroborating their basic–ultrabasic property. The TiO2 value is 3.6wt. %, indicating oceanic magma derivation. The industrial metals Pb, Cu, Ni and Zn were relatively similar with average values of 37.13, 23.96, 23.69, and 20.08ppm respectively, showing common protolith. The diorite and dolerite are enriched in trace elements Zr, Sr, with average concentration of 172.49, 109.73ppm, and relatively depleted in As and Au with values of 0.04 and 0.03ppm respectively. Petrogenetic analyses using ternary diagram TiO2–K2O–P2O5 for discriminating magma type, the dolerites and diorites all plot in continental basaltic field. In the AFM, and P2O5 versus Zr plots all the dolerites and diorites fall in the tholeiitic field, corroborating that they originated from tholeiitic basaltic magma, probably derived from lower crust/upper mantle. In the Na2O/Al2O3 versus K2O/Al2O3 diagram the dolerites and diorites all plot in the igneous field, the shale plot in metasedimentary field, while the ironstone fall on the boundary between igneous and metasedimentary fields indicating hybrid provenance.

Overview of Gemstone Resources in China

Gemstones are minerals of gem qualities used for adornment and decoration with the attributes of beauty, durability and rarity. Traditionally, although China has been regarded as the most important source for nephrite, over the past decades, a large variety of gemstone resources have been newly discovered in China owing to continuous exploration works. The vast land with various geological and geochemical backgrounds is rich in gemstone resources with potential for new deposits discoveries. In pegmatites, gemstones are related to granitic magma events and mainly occur in pegmatitic cavities, such as tourmaline, aquamarine, spodumene, spessartine, moonstone, quartz, apatite, and topaz. The eruption of Tertiary basaltic magma provides gem-quality sapphire, spinel, olivine, garnet, and zircon. The supergene oxidation zones of some copper and iron deposits in Hubei and Anhui province host gem-quality turquoise and malachite. Moreover, the formation of the nephrite deposit in China is mostly related to the carbonatite and serpentinite rocks involved in the metamorphic-metasomatic processes. This paper comprehensively introduces the distribution of gemstones deposits, as well as the gemological and mineralogical characteristics of gemstones in China. Our present investigation provides insights into the gemstone potential of China for further exploitation.

Magmatic architecture below the Okataina Volcanic Centre, Taupō Volcanic Zone, Aotearoa New Zealand, inferred from basalt geochemistry

The Okataina Volcanic Centre (OVC) is the most recently active rhyolitic volcanic centre in the Taupō Volcanic Zone, Aotearoa New Zealand. Although best known for its high rates of explosive rhyolitic volcanism, there are numerous examples of basaltic to basaltic-andesite contributions to OVC eruptions, ranging from minor involvement of basalt in rhyolitic eruptions to the exclusively basaltic 1886 C.E. Plinian eruption of Tarawera. To explore the basaltic component supplying this dominantly rhyolitic area, we analyse the textures and compositions (minerals and melt inclusions) of four basaltic eruptions within the OVC that have similar whole rock chemistry, namely: Terrace Rd, Rotomakariri, Rotokawau, and Tarawera. Data from these basaltic deposits provide constraints on the conditions of magma evolution and ascent in the crust prior to eruption, revealing that at least five different magma types (two basalts, two dacites, one rhyolite) are sampled during basaltic eruptions. The most abundant basaltic magma type is generated by cooling-induced crystallisation of a common, oxidised, basaltic melt at various depths throughout the crust. The volatile content of this melt was increased by protracted fluid-undersaturated crystallisation. All eruptions display abundant evidence for syn-eruptive mixing of the different magma types. Rotomakariri, consisting of a mafic crystal cargo mixed into a dacitic magma is the most extreme example of this process. Despite similar bulk compositions, comparable to other basaltic deposits in the region, these four OVC eruptions are texturally distinct as a consequence of their wide variation in eruption style.

Petrogenesis of the Jurassic Guiping Complex in the Southwestern South China Block: Insights into the Subduction Processes of the Paleo-Pacific Slab

Late Jurassic NE-trending A-type granitoids are widespread in the Shihang belt, South China, though their petrogenesis and geodynamic settings remain controversial. The Guiping complex is located on the southwest margin of the Shihang belt. In this study, the petrography, major and trace element geochemistry, whole-rock Sr-Nd isotopes, and zircon U-Pb geochronology of the Guiping complex were investigated. The Guiping complex is composed of the Fenghuangling and Xishan plutons; both plutons yielded zircon U-Pb ages of ca. 160 Ma. The Fenghuangling pluton has low SiO2 content of 54.26% to 60.31%, whereas the Xishan pluton exhibits high SiO2 content of 65.19% to 71.18%. Both of them are metaluminous and belong to the high-K calc-alkaline series and are enriched in large-ion lithophile elements (LILEs) such as Rb, Th, U, and Pb. The Fenghuangling and Xishan plutons showed enrichment in light rare earth elements (LREEs) and high-field strength elements (Nb, Ta, Zr, and Hf) and depletion in heavy rare earth elements (HREEs). Marked Nb and Ta negative anomalies were not observed. Due to the high contents of Zr + Ce + Nb + Y and high Ga/Al ratios, all the samples belonged to the group of A-type granites. The Fenghuangling and Xishan plutons had low ISr (mainly in the range of 0.7046–0.7058) and high εNd(t) (−0.60 to 1.94) values, though obviously different from those of the Precambrian basement in South China. Furthermore, they lie between the ocean island basalt (OIB) of the asthenosphere and the arc basaltic rocks of the enriched lithospheric mantle. Therefore, we proposed that the basaltic parental magma of the Guiping complex originated from partial melting of the enriched lithospheric mantle, which was metasomatized by asthenosphere-related OIB-type basaltic magma. Mafic microgranular enclaves in the Xishan pluton displayed positive Nb and Ta anomalies, which is consistent with OIB-type basalts. The enclaves also had similar Sr-Nd isotopic compositions to the Xishan pluton. That indicated that the enclaves were probably formed by mixing of the OIB-type basaltic magma and the Xishan pluton. In conclusion, the formation of the Late Jurassic NE-trending A-type granite belt was attributed to back-arc extension as a result of the rollback of the Paleo-Pacific Plate.

Geochemistry and Petrogenesis of Basic Paleogene Volcanic Rocks in Alamut Region

Structurally, the study area belongs to the tectonic range of the Central Alborz. The rocks were analyzed to detect main elements as well as rare and rare earth elements. Based on microscopic studies, the rocks in the region include basalt, trachyandesite and basaltic andesite with alkaline geochemical properties. According to geochemical studies, the early magma was affected by Nb, Ti, Ta, Eu negative anomalies, the enrichment of Rhizosphere rocks of rare earth elements (LRRE), high LREE/HREE ratio and low K/Nb ratio and high ratios of Th/Nb, La/Nb, Ba/Nb, Zr/ Nb magmatic contamination. The early basaltic magma has been formed of a garnet lherzolite mantle with phlogopite/pargasite by metasomatism at a pressure of 2.5-5.3 GPa at depths of more than 80-150 km. Structural evidence suggests the formation of these volcanic rocks in intercontinental rift zones. The formation of these rocks can be attributed to the effects of intercontinental extensional phases in deep faults during Eocene Alpine orogeny phases.