Theoretical studies on anionic clusters of sulfate anions and carbon dioxide, SO 4 −1/−2 (CO2) n , n = 1−4

2012 ◽  
Vol 131 (2) ◽  
Author(s):  
Friedrich Grein ◽  
Daniel M. Chevrier
Synlett ◽  
2017 ◽  
Vol 28 (18) ◽  
pp. 2439-2444 ◽  
Author(s):  
Frank Jensen ◽  
Troels Skrydstrup ◽  
Mathias Flinker ◽  
Sara Lopez ◽  
Dennis Nielsen ◽  
...  

Three disilanes, (CH3)3SiSi(CH3)3, Cl(CH3)2SiSi(CH3)2Cl, and Cl2(CH3)SiSi(CH3)Cl2, all representing components of the Direct Process residue for the industrial synthesis of chloromethylsilanes, were evaluated for their abilities to reduce carbon dioxide to carbon monoxide upon treatment with fluoride salts. In particular, Cl(CH3)2SiSi(CH3)2Cl proved to be highly efficient upon the use of stoichiometric amounts of potassium bifluoride. DFT calculations performed on the reduction steps with (CH3)3SiSi(CH3)3 and fluorinated analogues of this disilane suggest that the previously proposed pathway involving an intermediate silacarboxylic acid is plausible.


1982 ◽  
Vol 87 (B12) ◽  
pp. 10215 ◽  
Author(s):  
Fraser P. Fanale ◽  
W. Bruce Banerdt ◽  
R. Steven Saunders ◽  
L. A. Johansen ◽  
James R. Salvail

1980 ◽  
Vol 39 (6) ◽  
pp. 1519-1526 ◽  
Author(s):  
R.D. Amos ◽  
A.D. Buckingham ◽  
J.H. Williams

ChemInform ◽  
2010 ◽  
Vol 22 (19) ◽  
pp. no-no
Author(s):  
A. DEDIEU ◽  
C. BO ◽  
F. INGOLD

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