Thermodynamics of cosolvent effect of surface-active ionic liquids on the micellization of conventional surfactant

Author(s):  
Ummer Farooq ◽  
Nisar Ahmad Malik ◽  
Aabid Hussain Shalla
2015 ◽  
Vol 17 (21) ◽  
pp. 13992-14002 ◽  
Author(s):  
Shiba Sundar Dandpat ◽  
Moloy Sarkar

The present study demonstrates the aggregation behavior of rutaecarpine and the effect of surface active ionic liquids on the dissociation of the aggregates.


2019 ◽  
Vol 278 ◽  
pp. 145-155 ◽  
Author(s):  
Guowei Wang ◽  
Xiaoqing Xu ◽  
Yu Sun ◽  
Linghua Zhuang ◽  
Cheng Yao

2021 ◽  
Vol 19 ◽  
pp. 100369
Author(s):  
Dewi K.A. Kusumahastuti ◽  
Mariliis Sihtmäe ◽  
Villem Aruoja ◽  
Nicholas Gathergood ◽  
Anne Kahru
Keyword(s):  

RSC Advances ◽  
2016 ◽  
Vol 6 (58) ◽  
pp. 52781-52789 ◽  
Author(s):  
Juliusz Pernak ◽  
Kamil Czerniak ◽  
Agnieszka Biedziak ◽  
Katarzyna Marcinkowska ◽  
Tadeusz Praczyk ◽  
...  

A new family of herbicidal ionic liquids based on d-glucose and MCPA or 2,4-D anions has been synthesized and the physicochemical, surface active and herbicidal properties of the obtained salts were characterized.


2016 ◽  
Vol 69 (11) ◽  
pp. 1254 ◽  
Author(s):  
Jiequn Wu ◽  
Tianxiang Yin ◽  
Shaoxiong Shi ◽  
Weiguo Shen

The systematic investigation of the aggregation behaviours of newly synthesised surface-active ionic liquids 1-alkyl-3-methylimidazolium bis(2-ethylhexyl)sulfosuccinate ([Cnmim][AOT], n = 2, 3, 5, 6, 7) by various techniques is reported. The critical aggregation concentrations (CACs) and the standard Gibbs free energies of aggregation () were determined from measurements on conductivity, fluorescence, and surface tension, which suggested a stronger self-assembly ability in the bulk solution for [Cnmim][AOT] surfactants with longer alkyl chain cations. An interesting structure transition driven by the penetration of the imidazolium cation into the aggregate when n > 4 was found by analysis of the variations of the values of CAC, , the degree of counter ion binding (β), and the micropolarity (I1/I3) immediately after the CAC with changing alkyl chain length of the imidazolium cation, which was further confirmed by 1H NMR measurements.


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