Aggregation Behaviours of Surface-Active Ionic Liquids 1-Alkyl-3-methylimidazolium Bis(2-ethylhexyl)sulfosuccinate

2016 ◽  
Vol 69 (11) ◽  
pp. 1254 ◽  
Author(s):  
Jiequn Wu ◽  
Tianxiang Yin ◽  
Shaoxiong Shi ◽  
Weiguo Shen
Keyword(s):  
Ionic Liquids ◽  
Self Assembly ◽  
Alkyl Chain ◽  
Systematic Investigation ◽  
Bulk Solution ◽  
Free Energies ◽  
Imidazolium Cation ◽  
Structure Transition ◽  
Surface Active ◽  
Counter Ion Binding

The systematic investigation of the aggregation behaviours of newly synthesised surface-active ionic liquids 1-alkyl-3-methylimidazolium bis(2-ethylhexyl)sulfosuccinate ([Cnmim][AOT], n = 2, 3, 5, 6, 7) by various techniques is reported. The critical aggregation concentrations (CACs) and the standard Gibbs free energies of aggregation () were determined from measurements on conductivity, fluorescence, and surface tension, which suggested a stronger self-assembly ability in the bulk solution for [Cnmim][AOT] surfactants with longer alkyl chain cations. An interesting structure transition driven by the penetration of the imidazolium cation into the aggregate when n > 4 was found by analysis of the variations of the values of CAC, , the degree of counter ion binding (β), and the micropolarity (I1/I3) immediately after the CAC with changing alkyl chain length of the imidazolium cation, which was further confirmed by 1H NMR measurements.

Aggregation behavior of zwitterionic surface active ionic liquids with different counterions, cations, and alkyl chains

RSC Advances ◽  
2016 ◽  
Vol 6 (33) ◽  
pp. 27370-27377 ◽  
Author(s):  
Panpan Sun ◽  
Lijuan Shi ◽  
Fei Lu ◽  
Liqiang Zheng
Keyword(s):  
Ionic Liquids ◽  
Chain Length ◽  
Self Assembly ◽  
Alkyl Chain ◽  
Alkyl Chain Length ◽  
Aggregation Behavior ◽  
The Self ◽  
Alkyl Chains ◽  
Surface Active

The effects of anionic type, cationic structure and alkyl chain length are illustrated to regulate the self-assembly of zwitterionic SAILs.

Self-assembly of new surface active ionic liquids based on Aerosol-OT in aqueous media

2014 ◽  
Vol 428 ◽  
pp. 267-275 ◽  
Author(s):  
K. Srinivasa Rao ◽  
Praveen Singh Gehlot ◽  
Tushar J. Trivedi ◽  
Arvind Kumar
Keyword(s):  
Ionic Liquids ◽  
Self Assembly ◽  
Aqueous Media ◽  
Aerosol Ot ◽  
Surface Active

Protic Ionic Liquids Based on the Alkyl-Imidazolium Cation: Effect of the Alkyl Chain Length on Structure and Dynamics

2019 ◽  
Vol 123 (18) ◽  
pp. 4044-4054 ◽  
Author(s):  
Iqbaal Abdurrokhman ◽  
Khalid Elamin ◽  
Olesia Danyliv ◽  
Mohammad Hasani ◽  
Jan Swenson ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Chain Length ◽  
Alkyl Chain ◽  
Alkyl Chain Length ◽  
Protic Ionic Liquids ◽  
Imidazolium Cation ◽  
Structure And Dynamics ◽  
Cation Effect

scholarly journals The origin of surfactant amphiphilicity and self-assembly in protic ionic liquids

2015 ◽  
Vol 6 (11) ◽  
pp. 6189-6198 ◽  
Author(s):  
Andrew Dolan ◽  
Rob Atkin ◽  
Gregory G. Warr
Keyword(s):  
Ionic Liquids ◽  
Self Assembly ◽  
Alkyl Chain ◽  
Micelle Formation ◽  
Head Group ◽  
Protic Ionic Liquids

Surfactant alkyl chain, head-group and counterion solvation in protic ionic liquids differs from water, affecting micelle formation and structure.

scholarly journals Scrutinizing Self-Assembly, Surface Activity and Aggregation Behavior of Mixtures of Imidazolium Based Ionic Liquids and Surfactants: A Comprehensive Review

2021 ◽  
Vol 9 ◽  
Author(s):  
Harsh Kumar ◽  
Gagandeep Kaur
Keyword(s):  
Ionic Liquids ◽  
Surface Activity ◽  
Oil Recovery ◽  
Self Assembly ◽  
Carbon Capture ◽  
Aggregation Behavior ◽  
The Self ◽  
Mixed Micellization ◽  
Treatment Technologies ◽  
Surface Active

The desire of improving various processes like enhanced oil recovery (EOR), water treatment technologies, biomass extraction, organic synthesis, carbon capture etc. in which conventional surfactants have been traditionally utilized; prompted various researchers to explore the self-assembly and aggregation behavior of different kinds of surface-active molecules. Ionic liquids (ILs) with long alkyl chain present in their structure constitute the advantageous properties of surfactant and ILs, hence termed as surface-active ionic liquids (SAILs). The addition of ILs and SAILs significantly influence the surface-activity and aggregation behavior of industrially useful conventional surfactants. After a brief review of ILs, SAILs and surfactants, the prime focus is made on analyzing the self-assembly of SAILs and the mixed micellization behavior of conventional surfactants with different ILs.

scholarly journals Synthesis, self-assembly, bacterial and fungal toxicity, and preliminary biodegradation studies of a series ofl-phenylalanine-derived surface-active ionic liquids

2019 ◽  
Vol 21 (7) ◽  
pp. 1777-1794 ◽  
Author(s):  
Illia V. Kapitanov ◽  
Andrew Jordan ◽  
Yevgen Karpichev ◽  
Marcel Spulak ◽  
Lourdes Perez ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Self Assembly ◽  
Design Approach ◽  
Surface Active ◽  
Comprehensive Study

A comprehensive study devoted to designing green surface-active ionic liquids (SAILs) based on the “benign-of-design” approach results in finding greener alternatives.

Unprecedented self-assembled architectures of surface-active ionic liquids in aqueous medium

2018 ◽  
Vol 54 (19) ◽  
pp. 2432-2435 ◽  
Author(s):  
Gurbir Singh ◽  
Manvir Kaur ◽  
Markus Drechsler ◽  
Tejwant Singh Kang
Keyword(s):  
Ionic Liquids ◽  
Aqueous Solutions ◽  
Aqueous Medium ◽  
Self Assembly ◽  
First Report ◽  
Low Concentrations ◽  
Surface Active ◽  
Self Assembled

A first report on bilayer architectures from self-assembly of SAILs without any additive in aqueous solutions at very low concentrations.

Sign in / Sign up

Export Citation Format

Share Document