In this paper we study forward quantum Markov chains (QMC) defined on Cayley tree. A construction of such QMC is provided, namely we construct states on finite volumes with boundary conditions, and define QMC as a weak limit of those states which depends on the boundary conditions. Using the provided construction, we investigate QMC associated with XY-model on a Cayley tree of order two. We prove uniqueness of QMC associated with such a model, this means the QMC does not depend on the boundary conditions.