Increasing the service life of pellet car grate bars made of 40Х24Н12СЛ steel

Intercrystallite corrosion (ICC) is the main reason to decrease service life of pellet car grate bars made of steel 40Х24Н12СЛ. In the process of the study of microstructure of pellet car grate bars manufactured according to GOST 977–88, the structure defects were established that increase the tendency to ICC. To prevent the ICC of the bars, a mode of heat treatment was elaborated, consisting of two basic operations: air hardening with preliminary exposure within 80 minutes at the temperature 1100 °С, followed by tempering within 150 minutes at the temperature 900 °С. The study of the structure of the pilot grate bar showed that the selected mode of the hardening enables to dissolve the carbide network in the structure of the detail and crash large carbides, and the subsequent tempering contributes to the growth of the carbide phase in the entire volume of metal, partially remaining in the structure after hardening. It was shown that the proposed mode of the heat treatment contributes to bringing the structure of the metal to a more “equilibrium” state, which will allow to exclude the formation of large carbides and carbide network, growth and coagulation along the grain boundary. Results of tests of a pilot batch of grate bars installed at an industrial induration machine with a working area of 768 m2 and operating temperature of 20–1310°С presented. It was established that the elaborated technology ensures absence of casting defects in the grate bars – cracks and warping, inclination of the grate bars to ICC, increased by 23.13% heat resistance compared to the reference grate bars of foreign supply due to the globular form of carbide secretions with a minimum length of borders along which the metal matrix is depleted by chrome. Industrial testing of the grate bars manufactured under the experimental technology has proved the practical significance and applicability of the performed research.

Defects of diamond crystal structure as an indicator of crystallogenesis

Based on the study of a representative collections of diamonds from diamondiferous formations of the Urals and deposits of the Arkhangelsk and Yakutian diamond provinces, we established patterns of zonal and sectoral distribution of crystal structure defects in crystals of different morphological types, identified the specifics of crystals formed at different stages of crystallogenesis and performed a comprehensive analysis of constitutional and population diversity of diamonds in different formations. We identified three stages in the crystallogenesis cycle, which correspond to normal and tangential mechanisms of growth and the stage of changing crystal habit shape. At the stage of changing crystal habit shape, insufficient carbon supersaturation obstructs normal growth mechanism, and the facets develop from existing surfaces. Due to the absent stage of growth layer nucleation, formation of new {111} surfaces occurs much faster compared to tangential growth mechanism. This effect allows to explain the absence of cuboids with highly transformed nitrogen defects at the A-B1 stage: they have all been refaceted by a regenerative mechanism. Based on the revealed patterns, a model of diamond crystallogenesis was developed, which takes into account the regularities of growth evolution, thermal history and morphological diversity of the crystals. The model implies the possibility of a multiply repetitive crystallization cycle and the existence of an intermediate chamber; it allows to explain the sequence of changes in morphology and defect-impurity composition of crystals, as well as a combination of constitutional and population diversity of diamonds from different geological formations.

Structure, Defects and Microwave Dielectric Properties of Al-doped and Al/Nd Co-doped Ba4Nd9.33Ti18O54 Ceramics

Ba4Nd9.33Ti18-zAl4z/3O54 (BNT-A, 0 ≤ z ≤ 2) and Ba4Nd9.33+z/3Ti18-zAlzO54 (BNT-AN, 0 ≤ z ≤ 2) ceramics were prepared by solid state method, and the effects of the two doping methods on microwave dielectric properties were compared. As the doping amount z increased, the relative dielectric constant (εr) and the temperature coefficient of resonant frequency (τf) values of the ceramics decreased, and the quality factor (Q, usually expressed by Q×f, where f is the resonant frequency) of the ceramics obviously increased when z ≤ 1.5. With the same z value, the εr and Q×f values of Al/Nd co-doped ceramics are both higher than those of Al-doped ceramics. Rietveld refinement, Raman spectroscopy and thermally stimulated depolarization current (TSDC) technique were applied to clarify the relationship among the structure, defects and microwave dielectric properties. It is shown that the Q×f values of those ceramics were closely related to the strength of the A-site cation vibration and the concentration of oxygen vacancies (B). Excellent microwave dielectric properties of εr = 72.2, Q×f = 16480 GHz, and τf = +14.3 ppm/℃ were achieved in BNT-AN ceramics with z = 1.25.