Thermodynamics of Transfer of Some Alkyl Acetates from Water to Water–Ethanol Mixtures

2002 ◽  
Vol 133 (7) ◽  
pp. 959-973
Author(s):  
Nataša Šegatin ◽  
Cveto Klofutar
Keyword(s):  
Thermodynamics Of Transfer ◽  
Alkyl Acetates

An analysis of the thermodynamics of transfer of polar non-electrolytes from water to aqueous concentrated salt solutions

1977 ◽  
Vol 30 (12) ◽  
pp. 2597 ◽  
Author(s):  
RF Cross ◽  
PT McTigue
Keyword(s):  
Activity Coefficient ◽  
Scaled Particle Theory ◽  
Enthalpies Of Solution ◽  
Polar Group ◽  
Methyl Ethyl ◽  
Particle Theory ◽  
Salt Solutions ◽  
Thermodynamics Of Transfer ◽  
Alkyl Side Chains ◽  
Alkyl Acetates

A calorimeter has been constructed and used to determine the limiting enthalpies of solution (ΔHS) of a series of alkyl acetates (methyl, ethyl, propyl, butyl and t-butyl) in water and aqueous solutions of some of the following salts: LiCl, NaCl, KCl, CsCl, KF, KBr, NaNO3 and NaClO4. These measurements are combined with previous activity coefficient determinations to obtain the thermodynamics of transfer for the esters. In the case of transfer to NaCl solutions, scaled-particle theory calculations are used to determine the thermodynamics of cavity transfer, which, when combined with the experimental total-transfer quantities, give rise to a set of quantities that we have called the interaction transfer quantities. These quantities indicate that the predominant factors in the transfer of neutral molecules containing both polar and non-polar segments from water to NaCl solutions are the transfer of the cavity and of the interactions of the polar group. The interactions of the alkyl side chains are shown to be similar to those of alkane molecules.

Gas phase pyrolysis of alkyl acetates

2010 ◽  
Vol 82 (11) ◽  
pp. 1123-1154 ◽  
Author(s):  
J. C. Scheer ◽  
E. C. Kooyman ◽  
F. L. J. Sixma
Keyword(s):  
Gas Phase ◽  
Alkyl Acetates

Factors in Aldol Condensations of Alkyl Acetates with Benzophenone and Reversals by Sodium Amide Versus Lithium Amide. Metallic Cation Effects1

1960 ◽  
Vol 25 (8) ◽  
pp. 1296-1302 ◽  
Author(s):  
CHARLES R. HAUSER ◽  
WILLIAM R. DUNNAVANT
Keyword(s):  
Lithium Amide ◽  
Metallic Cation ◽  
Alkyl Acetates ◽  
Amide Versus ◽  
Sodium Amide

Heats of mixing and contact interaction of hydrocarbons with n-alkyl acetates

1981 ◽  
Vol 85 (9) ◽  
pp. 1261-1264 ◽  
Author(s):  
D. D. Deshpande ◽  
C. S. Prabhu
Keyword(s):  
Contact Interaction ◽  
Heats Of Mixing ◽  
Alkyl Acetates

The thermodynamics of transfer of phenol and aniline between nonpolar and aqueous environments

1978 ◽  
Vol 82 (6) ◽  
pp. 675-678 ◽  
Author(s):  
Kenneth J. Breslauer ◽  
Lucia Witkowski ◽  
Kristina Bulas
Keyword(s):  
Thermodynamics Of Transfer ◽  
Aqueous Environments

scholarly journals Synthesis of Alkyl Acetates from Ketene and Aliphatic Alcohols.

1956 ◽  
Vol 59 (12) ◽  
pp. 1415-1417
Author(s):  
Toshizo Isoshima
Keyword(s):  
Aliphatic Alcohols ◽  
Alkyl Acetates

Investigation on thermodynamic properties and spectroscopic studies of binary mixtures of 1, 2, 4-trichlorobenzene with alkyl acetates (C1-C5) at T = (303.15 to 318.15) K

2021 ◽  
Vol 36 ◽  
pp. 100781
Author(s):  
R. Raju ◽  
S. Ravikumar ◽  
K. Sivakumar ◽  
P. Bhanuprakash ◽  
V. Pandiyan
Keyword(s):  
Thermodynamic Properties ◽  
Binary Mixtures ◽  
Spectroscopic Studies ◽  
Alkyl Acetates
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