scholarly journals Triphenyl phosphine oxide and carbazole-based polymer host materials for green phosphorescent organic light-emitting diodes

2017 ◽  
Vol 35 (5) ◽  
pp. 611-622 ◽  
Author(s):  
Hong-ji Jiang ◽  
Qing-wei Zhang ◽  
Xu He ◽  
Xiao-lin Zhang ◽  
Xin-wen Zhang
Keyword(s):  
Phosphine Oxide ◽  
Light Emitting Diodes ◽  
Organic Light Emitting Diodes ◽  
Triphenyl Phosphine ◽  
Light Emitting ◽  
Organic Light ◽  
Host Materials ◽  
Polymer Host ◽  
Triphenyl Phosphine Oxide

Tuning peripheral group density in ternary phosphine oxide hosts for low-voltage-driven yellow PhOLEDs

2015 ◽  
Vol 3 (26) ◽  
pp. 6709-6716 ◽  
Author(s):  
Jing Li ◽  
Zhensong Zhang ◽  
Chunmiao Han ◽  
Dongxue Ding ◽  
Yi Zhao ◽  
...  
Keyword(s):  
Phosphine Oxide ◽  
Light Emitting Diodes ◽  
Low Voltage ◽  
Organic Light Emitting Diodes ◽  
Diphenylphosphine Oxide ◽  
Light Emitting ◽  
Organic Light ◽  
Host Materials ◽  
Group Density

Fluorene and diphenylphosphine oxide were employed as peripheral groups to construct ternary host materials DBFxPODEFn with benzofuran as a core, which realized the low-voltage-driven efficient yellow phosphorescence organic light-emitting diodes.

Spatially optimized quaternary phosphine oxide host materials for high-efficiency blue phosphorescence and thermally activated delayed fluorescence organic light-emitting diodes

2015 ◽  
Vol 3 (43) ◽  
pp. 11385-11396 ◽  
Author(s):  
Dongxue Ding ◽  
Zhen Zhang ◽  
Ying Wei ◽  
Pengfei Yan ◽  
Hui Xu
Keyword(s):  
Phosphine Oxide ◽  
High Efficiency ◽  
Light Emitting Diodes ◽  
Spatial Optimization ◽  
Delayed Fluorescence ◽  
Organic Light Emitting Diodes ◽  
Light Emitting ◽  
Thermally Activated ◽  
Organic Light ◽  
Host Materials

Spatial optimization of host materials for highly efficient blue organic light-emitting diodes was rationally performed on the basis of a series of ternary and quaternary phosphine oxide materials.

Fluorinated Poly(N-vinylcarbazole) Host for Triplet Energy Confinement on Phosphorescent Emitter in Organic Light-emitting Diodes

2009 ◽  
Vol 1197 ◽  
Author(s):  
Yukitami Mizuno ◽  
Isao Takasu ◽  
Shuichi Uchikoga ◽  
Shintaro Enomoto ◽  
Tomoaki Sawabe ◽  
...  
Keyword(s):  
Light Emitting Diodes ◽  
Energy Gap ◽  
Organic Light Emitting Diodes ◽  
Lumo Energy ◽  
Light Emitting ◽  
Energy Gaps ◽  
Organic Light ◽  
Host Materials ◽  
Homo Lumo ◽  
Polymer Host

AbstractFluorinated carbazoles as host materials have been investigated for highly efficient organic light emitting diodes (OLEDs). By molecular orbital calculations, we found that fluorinations at position 2, 4, 5 and 7 of carbazole ring were effective for widening HOMO-LUMO energy gap. The energy gaps of our synthesized 2,7-difluorocarbazole (F2-Cz) and 2,4,5,7-tetrafluorocarbazole (F4-Cz), were estimated to be 3.71 eV and 3.87 eV by the absorption spectra, respectively. These energy gaps were higher than that of the non-substituted carbazole (Cz, 3.59 eV). We synthesized poly(N-vinyl-2,7-difluorocarbazole) (F2-PVK) and poly(N-vinyl-2,4,5,7-tetrafluorocarbazole) (F4-PVK) as solution processable polymer host materials. However, the F4-PVK was found to be an unsolved polymer. The F2-PVK could be compared with non substituted poly(N-vinylcarbazole) (PVK) in OLEDs. The emission layer (EML) contained iridium(III) bis [(4,6-di-fluorophenyl)-pyridinato-N,C2′] picolinate (FIrpic) as a blue phosphorescent dopant, and iridium(III) bis [2-(9,9-dihexylfluorenyl)-1-pyridine] acetylacetonate as a yellow dopant. The white OLED with the F2-PVK showed 1.4 times higher luminous current efficiency (24 cd/A) than the PVK (17 cd/A). These data show that the excitation energy is confined on dopants by using fluorinated polymer host material with higher T1 corresponding to wider HOMO-LUMO energy gap.

meta-Linked spirobifluorene/phosphine oxide hybrids as host materials for deep blue phosphorescent organic light-emitting diodes

2013 ◽  
Vol 14 (7) ◽  
pp. 1924-1930 ◽  
Author(s):  
Lin-Song Cui ◽  
Shou-Cheng Dong ◽  
Yuan Liu ◽  
Mei-Feng Xu ◽  
Qian Li ◽  
...  
Keyword(s):  
Phosphine Oxide ◽  
Light Emitting Diodes ◽  
Organic Light Emitting Diodes ◽  
Light Emitting ◽  
Deep Blue ◽  
Organic Light ◽  
Host Materials ◽  
Blue Phosphorescent

High-efficiency red, green and blue phosphorescent homojunction organic light-emitting diodes based on bipolar host materials

2011 ◽  
Vol 12 (5) ◽  
pp. 843-850 ◽  
Author(s):  
Chao Cai ◽  
Shi-Jian Su ◽  
Takayuki Chiba ◽  
Hisahiro Sasabe ◽  
Yong-Jin Pu ◽  
...  
Keyword(s):  
High Efficiency ◽  
Light Emitting Diodes ◽  
Organic Light Emitting Diodes ◽  
Light Emitting ◽  
Organic Light ◽  
Host Materials ◽  
Blue Phosphorescent
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