scholarly journals High-triplet-energy Bipolar Host Materials Based on Phosphine Oxide Derivatives for Efficient Sky-blue Thermally Activated Delayed Fluorescence Organic Light-emitting Diodes with Reduced Roll-off

2019 ◽  
Vol 48 (10) ◽  
pp. 1225-1228
Author(s):  
Jong Uk Kim ◽  
Michael Y. Wong ◽  
Shiv Kumar ◽  
Oliver G. Hayes ◽  
Finlay Duncan ◽  
...  
Author(s):  
Sung Yong Byun ◽  
Kyung Hyung Lee ◽  
Jun Yeob Lee

The effect of lowest unoccupied molecular orbital (LUMO) management of high triplet energy electron transport type hosts on the device performance of blue thermally-activated delayed fluorescence (TADF) organic light-emitting diodes...


2015 ◽  
Vol 3 (43) ◽  
pp. 11385-11396 ◽  
Author(s):  
Dongxue Ding ◽  
Zhen Zhang ◽  
Ying Wei ◽  
Pengfei Yan ◽  
Hui Xu

Spatial optimization of host materials for highly efficient blue organic light-emitting diodes was rationally performed on the basis of a series of ternary and quaternary phosphine oxide materials.


2020 ◽  
Vol 20 (11) ◽  
pp. 7191-7195
Author(s):  
JaMin Lee ◽  
Sae Won Lee ◽  
Young Sik Kim

Novel thermally activated delayed fluorescence (TADF) host materials for blue electrophosphores-cence were designed by combining the electron acceptor dibenzothiophene (DBT) unit and the electron donor acridine derivatives into a single molecular unit by density functional theory (DFT). Depending on the optimal charge transfer, DFT and time-dependent DFT (TD-DFT) calculations for the ground state were performed to obtain the energy of the singlet (S1) and triplet (T1) excited states of the TADF material for Hartree-Fock percentage of TD-DFT. The sufficiently large separation between the HOMO and LUMO resulted in a small difference in energy (ΔEST) between the S1 and T1 states using DFT and TD-DFT calculations. The host molecules retained high triplet energy and showed great potential for use in blue organic light-emitting diodes (OLED). The results showed that these molecules are a good TADF host materials because they have a low barrier to hole and electron injection with a balanced charge transporting property for both holes and electrons, and a small ΔEST.


2015 ◽  
Vol 3 (6) ◽  
pp. 1208-1224 ◽  
Author(s):  
Godumala Mallesham ◽  
Chidirala Swetha ◽  
Surukonti Niveditha ◽  
Maneesha Esther Mohanty ◽  
Nanubolu Jagadeesh Babu ◽  
...  

Efficient electron transporting blue emitting materials obtained from excimer emission assisted by thermally activated delayed fluorescence.


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