Stress-Induced Uphill Diffusion with Interfacial Contact Loss in Solid-State Electrodes

2021 ◽  
Author(s):  
Yanfei Zhao ◽  
Dingxin Shi ◽  
Bo Lu ◽  
Junqian Zhang
Keyword(s):  
Solid State ◽  
Uphill Diffusion ◽  
Interfacial Contact

scholarly journals Insights into interfacial effect and local lithium-ion transport in polycrystalline cathodes of solid-state batteries

2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Shuaifeng Lou ◽  
Qianwen Liu ◽  
Fang Zhang ◽  
Qingsong Liu ◽  
Zhenjiang Yu ◽  
...  
Keyword(s):  
Solid State ◽  
Ion Transport ◽  
Chemical Potential ◽  
Lithium Ion ◽  
Local Environment ◽  
Underlying Mechanism ◽  
Transport Kinetics ◽  
Potential Force ◽  
Interfacial Contact ◽  
Solid State Batteries

Abstract Interfacial issues commonly exist in solid-state batteries, and the microstructural complexity combines with the chemical heterogeneity to govern the local interfacial chemistry. The conventional wisdom suggests that “point-to-point” ion diffusion at the interface determines the ion transport kinetics. Here, we show that solid-solid ion transport kinetics are not only impacted by the physical interfacial contact but are also closely associated with the interior local environments within polycrystalline particles. In spite of the initial discrete interfacial contact, solid-state batteries may still display homogeneous lithium-ion transportation owing to the chemical potential force to achieve an ionic-electronic equilibrium. Nevertheless, once the interior local environment within secondary particle is disrupted upon cycling, it triggers charge distribution from homogeneity to heterogeneity and leads to fast capacity fading. Our work highlights the importance of interior local environment within polycrystalline particles for electrochemical reactions in solid-state batteries and provides crucial insights into underlying mechanism in interfacial transport.

Enhancing interfacial contact in all solid state batteries with a cathode-supported solid electrolyte membrane framework

2019 ◽  
Vol 12 (3) ◽  
pp. 938-944 ◽  
Author(s):  
Xinzhi Chen ◽  
Wenjun He ◽  
Liang-Xin Ding ◽  
Suqing Wang ◽  
Haihui Wang
Keyword(s):  
Solid State ◽  
Electrochemical Performance ◽  
Solid Electrolyte ◽  
Electrolyte Membrane ◽  
Interfacial Contact ◽  
Solid State Batteries ◽  
All Solid State Batteries

A cathode-supported solid electrolyte membrane framework with enhanced interfacial contact can significantly improve the electrochemical performance of all solid state batteries.

Enhancing Interfacial Contact in Solid‐State Batteries with a Gradient Composite Solid Electrolyte

Small ◽  
2021 ◽  
pp. 2006578
Author(s):  
Chenglong Deng ◽  
Nan Chen ◽  
Chuanyu Hou ◽  
Hanxiao Liu ◽  
Zhiming Zhou ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolyte ◽  
Interfacial Contact ◽  
Solid State Batteries ◽  
Composite Solid Electrolyte ◽  
Composite Solid

scholarly journals Interfacial Contact Process Controlled by Superplastic Flow in Solid-state Bonding of Superplastic High Carbon Steel

2015 ◽  
Vol 33 (2) ◽  
pp. 67s-70s
Author(s):  
Zhonghao Heng ◽  
Touma Matsushima ◽  
Yusuke Nashiki ◽  
Masakatsu Maeda ◽  
Keke Zhang ◽  
...  
Keyword(s):  
Solid State ◽  
Carbon Steel ◽  
High Carbon Steel ◽  
Contact Process ◽  
Superplastic Flow ◽  
High Carbon ◽  
Solid State Bonding ◽  
Interfacial Contact

Interrelated interfacial issues between a Li7La3Zr2O12-based garnet electrolyte and Li anode in the solid-state lithium battery: a review

2021 ◽  
Author(s):  
Lijie Yang ◽  
Zaili Lu ◽  
Yuanxue Qin ◽  
Chen Wu ◽  
Chuankai Fu ◽  
...  
Keyword(s):  
Solid State ◽  
Lithium Battery ◽  
The Poor ◽  
Interfacial Contact

The interrelated LLZO-BG/Li interfacial issues: the air instability of LLZO-BG and its instability with Li anode will induce the poor LLZO-BG/Li interfacial contact; the poor contact will accelerate the formation of Li dendrite.

Co3S4@Li7P3S11 Hexagonal Platelets as Cathodes with Superior Interfacial Contact for All-Solid-State Lithium Batteries

2020 ◽  
Vol 12 (12) ◽  
pp. 14079-14086 ◽  
Author(s):  
Jiamin Shi ◽  
Gaozhan Liu ◽  
Wei Weng ◽  
Liangting Cai ◽  
Qiang Zhang ◽  
...  
Keyword(s):  
Solid State ◽  
Lithium Batteries ◽  
Interfacial Contact

scholarly journals Three-dimensional “skin-framework” hybrid network as electroactive material platform for high-performance solid-state asymmetric supercapacitor

RSC Advances ◽  
2019 ◽  
Vol 9 (23) ◽  
pp. 12877-12885
Author(s):  
Liaoyuan Xia ◽  
Shaoheng Hu ◽  
Xueqin Zhang ◽  
Le Huang ◽  
Yu Liao ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Solid State ◽  
High Performance ◽  
Three Dimensional ◽  
Hybrid Network ◽  
Asymmetric Supercapacitor ◽  
High Electrical Conductivity ◽  
Electroactive Material ◽  
Interfacial Contact ◽  
3D Skin

3D “skin-framework” architecture of the MCN with large interfacial contact area and high electrical conductivity enable it to serve as a powerful electroactive platform for high-performance solid-state MnO2-MCN//AC-MCN ASC device.

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