Improvement of the anaerobic treatment of potato processing wastewater in a UASB reactor by co-digestion with glycerol

2007 ◽  
Vol 30 (5) ◽  
pp. 861-867 ◽  
Author(s):  
Jingxing Ma ◽  
Mariane Van Wambeke ◽  
Marta Carballa ◽  
Willy Verstraete
1997 ◽  
Vol 35 (8) ◽  
pp. 247-253 ◽  
Author(s):  
Herbert H. P. Fang ◽  
Ivan W. C. Lau ◽  
Denis W. C. Chung

The effects of nine common aromatic pollutants from chemical industry on the bioactivity of anaerobic granules were examined. The granules were obtained from an upflow anaerobic sludge blanket (UASB) reactor treating wastewater containing colloidal starch. The specific methanogenic activities (SMA) of granules were measured at 37°C in serum vials using 3000 mg/l of colloidal starch as substrate, plus individual pollutants at various concentrations. The toxicity was expressed by the IR50 and IC50 values, i.e. the toxicant/biomass ratio and concentration at which levels the granules exhibited only 50% of their original bioactivities. Results showed that in general the granules exhibited mild resistance to toxicity of aromatic pollutants, probably due to the granules' layered microstructure. The toxicities, which were dependent on the nature of chemical functional group, of the aromatic pollutants were in the following descending order: cresols > phenol > hydroxyphenols/phthalate > benzoate. There was only marginal difference between the toxicity of the steric isomers. For the seven phenolic pollutants, the more hydrophobic the functional group the higher the toxicity. The granules' resistance to toxicity suggested the plausibility of anaerobic treatment of wastewater from the chemical industry.


1985 ◽  
Vol 17 (1) ◽  
pp. 61-75 ◽  
Author(s):  
L H A Habets ◽  
J H Knelissen

Within the holding of Bührmann-Tetterode NV, 7 Dutch paper and board mills are operating, all of them using mainly waste paper as raw material. While three of them completely closed their watercircuits, two other mills put into practice biological waste water treatment namely anaerobic and anaerobic/aerobic. Number 6 is realising an anaerobic plant this year and for number 7 research is still being carried out, dealing with several unfavourable aspects. In September 1981 research for anaerobic treatment (UASB reactors) was started. After good results had been achieved on laboratory scale (301), further investigations were started on semitechnical scale (50 m3). In both cases the anaerobic seed sludge granulated after a while and loadings up to 20 kg COD/m3.d could be handled. COD-removal was 70 per cent, even when the hydraulic retention time was only 2.5 hours. In April 1983 a 70 m3 practical scale UASB reactor was started up at the solid board mill of Ceres. In October 1983 a full scale plant was started up at Papierfabriek Roermond. This plant consists of a 1,000 m3 UASB reactor and a 70 m3 gasholder. It has been designed and constructed by Paques BV and is used for pretreatment of effluent, in order to reduce the loading of the activated sludge plant. Besides energy savings on the oxygen input, about 1 million m3/year of biogas is being generated and is used for steamproduction. Both plants are working satisfactorily. Investment costs appeared to be relatively low. At Ceres, pay-out time is 1.5 year, while at Papierfabriek Roermond waste water treatment is cheaper than before, although capacity is doubled.


1997 ◽  
Vol 36 (2-3) ◽  
pp. 237-248 ◽  
Author(s):  
Robbert Kleerebezem ◽  
Joost Mortier ◽  
Look W. Hulshoff Pol ◽  
Gatze Lettinga

During petrochemical production of purified terephthalic acid (PTA, 1,4-benzene dicarboxylic acid), a large quantity of concentrated effluent is produced. Main polluting compounds in this wastewater are terephthalic acid, acetic acid and benzoic acid in decreasing order of concentration. Acetic acid and benzoic acid are known to be rapidly degraded in high rate anaerobic treatment systems, such as Upflow Anaerobic Sludge Bed (UASB) reactors. Concerning the kinetics of anaerobic mineralization of terephthalic acid, however, no information is available in literuature. Therefore our work focused on the anaerobic degradation of neutralized terephthalic acid (disodium terephthalate) in laboratory scale UASB-reactors and batch reactors. It was found that high rate anaerobic treatment of terephthalate was difficult to obtain due to the low growth rate (μ ≈ 0.04 day−1) of the terephthalate mineralizing mixed culture. The maximum removal capacity of a lab-scale UASB-reactor was found to be 3.9 g COD.1−1 .day−1 at a loading rate of 4.5 g COD.1−1 .day−1 and a hydraulic retention time of 24 hours. Terephthalate was used as sole carbon source during these experiments. Addition of small amounts of sucrose (co-substrate) to the influent, as a source of reducing equivalents, was found to have a negative influence on the anaerobic degradation of terephthalate. Also benzoate was found to inhibit the mineralization of terephthalate. Batch-toxicity experiments showed that terephthalate is not toxic to any of the species involved in its mineralization. Based on these observations, a staged anaerobic reactor system is suggested for the anaerobic pre-treatment of PTA-wastewater.


2001 ◽  
Vol 44 (4) ◽  
pp. 189-195 ◽  
Author(s):  
J. B. van Lier ◽  
P. N.L. Lens ◽  
L. W. Hulshoff Pol

Stringent environmental laws in Europe and Northern America lead to the development towards closure of the process water streams in pulp and paper mills. Application of a "zero-discharge" process is already a feasible option for the board and packaging paper industry, provided in-line treatment is applied. Concomitant energy conservation inside the mill results in process water temperatures of 50-60°C. Thermophilic anaerobic treatment complemented with appropriate post-treatment is considered as the most cost-effective solution to meet re-use criteria of the process water and to keep its temperature. In the proposed closed-cycle, the anaerobic treatment step removes the largest fraction of the biodegradable COD and eliminates “S” as H2S from the process stream, without the use of additional chemicals. The anaerobic step is regarded as the only possible location to bleed "S" from the process water cycle. In laboratory experiments, the effect of upward liquid velocity (Vupw) and the specific gas loading rate (Vgas) on the S removal capacity of thermophilic anaerobic bio-reactors was investigated. Acidifying, sulphate reducing sludge bed reactors were fed with partly acidified synthetic paper mill wastewater and were operated at 55°C and pH 6. The reactors were operated at organic loading rates up to 50 g COD.l−1.day−1 at COD/SO42- ratios of 10. The effect of Vupw was researched by comparing the performance of a UASB reactor operated at 1.0 m.h−1 and an EGSB reactor, operated at 6.8 m.h−1. The Vupw had a strong effect on the fermentation patterns. In the UASB reactor, acidification yielded H2, acetate and propionate, leading to an accumulation of reducing equivalents. These were partly disposed of by the production of n-butyrate and n-valerate from propionate. In the EGSB reactor net acetate consumption was observed as well as high volumetric gas (CO2 and CH4) production rates. The higher gas production rates in the EGSB reactor resulted in higher S-stripping efficiencies. The effect of Vgas was further researched by comparing 2 UASB reactors which were sparged with N2 gas at a specific gas loading rate of 30 m3.m−2.day−1. In contrast to the regular UASB reactors, the gas-supplied UASB showed a more stable performance when the organic loading rates were increased. Also, the H2S stripping efficiency was 3-4 times higher in the gas-supplied UASB, reaching values of 67%. Higher values were not obtained owing to the relatively poor sulphate reduction efficiencies.


1982 ◽  
Vol 17 (1) ◽  
pp. 63-74 ◽  
Author(s):  
R.C. Landine ◽  
G.J. Brown ◽  
A.A. Cocci ◽  
T. Viraraghavan

Abstract A laboratory bench-scale study using a unified anaerobic fermenter-filter system (referred to as a BVF-HAF system) was conducted at room temperature over an 8 month period on potato processing wastewater for the purpose of verifying a proposed full-scale design concept. In addition to two-stage anaerobic treatment, the first stage anaerobic effluent (BVF effluent) was subjected to aerobic polishing in a simulated facultative aerated lagoon with a retention of 4 days. The basic design conditions entailed treatment of a clarified potato wastewater with a COD of 7600 mg/L and a retention of 4 d in the BVF (loading 1.71 kg/m3.d). After over-coming an upset condition believed due to toxicity of the vacuum filtrate feed, the model performed well achieving 78.9% COD removal in the BVF plus 5 3.4% in the HAF for a combined total of 90.2%. When the BVF effluent was aerated the combined BVF - aerated lagoon removal reached 94.8%.


2011 ◽  
Vol 64 (8) ◽  
pp. 1629-1635 ◽  
Author(s):  
M. Esparza Soto ◽  
C. Solís Morelos ◽  
J. J. Hernández Torres

The aim of this work was to evaluate the performance of a pilot-scale upflow anaerobic sludge blanket (UASB) reactor during the treatment of cereal-processing industry wastewater under low-temperature conditions (17 °C) for more than 300 days. The applied organic loading rate (OLRappl) was gradually increased from 4 to 6 and 8 kg CODsol/m3d by increasing the influent soluble chemical oxygen demand (CODsol), while keeping the hydraulic retention time constant (5.2 h). The removal efficiency was high (82 to 92%) and slightly decreased after increasing the influent CODsol and the OLRappl. The highest removed organic loading rate (OLRrem) was reached when the UASB reactor was operated at 8 kg CODsol/m3d and it was two times higher than that obtained for an OLRappl of 4 kg CODsol/m3d. Some disturbances were observed during the experimentation. The formation of biogas pockets in the sludge bed significantly complicated the biogas production quantification, but did not affect the reactor performance. The volatile fatty acids in the effluent were low, but increased as the OLRappl increased, which caused an increment of the effluent CODsol. Anaerobic treatment at low temperature was a good option for the biological pre-treatment of cereal processing industry wastewater.


2001 ◽  
Vol 44 (4) ◽  
pp. 33-40 ◽  
Author(s):  
T. Elmitwalli ◽  
Gr. Zeeman ◽  
G. Lettinga

The results of research concerning the feasibility of anaerobic treatment of domestic sewage at low temperature are summarized in this article. The batch tests demonstrated a high biodegradability of domestic sewage at 20°C (74%). Both batch and continuous experiments for the treatment of domestic sewage showed that the removal of SS prior to anaerobic treatment of domestic sewage not only provides a stable reactor performance but also improves the removal of both colloidal (CODcol) and dissolved COD (CODdis). The results of the pre-treatment of domestic sewage in an anaerobic filter (AF) and an anaerobic hybrid (AH) reactor showed that the AF reactor is an efficient process for the removal of suspended COD (CODss), viz. 82%, at an HRT of 4 h and 13°C. The novel AF reactor consists of vertical sheets of reticulated polyurethane foam with knobs, where the biomass was only in attached form. For the treatment of pre-settled sewage at 13°C, the AH reactor, with granular sludge, showed a higher total COD (CODt) removal than the UASB reactor as a result of higher CODcol removal. Therefore, the performance of a two-step system, AF+AH (with granular sludge) reactor, was investigated with different HRTs at 13°C. For optimization of CODss and CODdis an HRT of 4+4 h is needed, while for optimization of CODcol removal an HRT of 4+8 h is required. A CODt removal of 71% was achieved with 60% conversion to methane from the removed CODt when the AF+AH system was operated at an HRT of 4+8 h at 13°C.


1991 ◽  
Vol 12 (4) ◽  
pp. 355-362 ◽  
Author(s):  
P.A. García ◽  
J.L Rico ◽  
F. Fdz‐Polanco

2015 ◽  
Vol 72 (8) ◽  
pp. 1383-1389 ◽  
Author(s):  
M. M. Nakazawa ◽  
W. R. S. Silva Júnior ◽  
M. T. Kato ◽  
S. Gavazza ◽  
L. Florencio

In this study, we evaluated the use of an up-flow anaerobic sludge blanket (UASB) reactor to treat crude glycerol obtained from cottonseed biodiesel production. The laboratory-scale UASB reactor (7.0 L) was operated at ambient temperature of 26.5°C with chemical oxygen demand (COD) concentrations between 0.5 and 8.0 g/L. The volatile fatty acid contents, pH, inorganic salt contents and biogas production were monitored during a 280-day experimental period. Molecular biology techniques were used to assess the microbial diversity in the bioreactor. The reactor achieved COD removal efficiencies of up to 92% except during one phase when the efficiency decreased to 81%. Biogas production remained stable throughout the experimental period, when the fraction converted to methane reached values as high as 68%. The profile of the denaturing gradient gel electrophoresis (DGGE) bands suggested slight changes in the microbial community during reactor operation. The overall results indicated that the crude glycerol from biodiesel production can serve as a suitable substrate for anaerobic degradation with a stable reactor performance and biogas production as long as the applied organic loads are up to 8.06 kg COD/m3·d.


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