Concentrations of toxic heavy metals and trace elements in raw milk of Simmental and Holstein-Friesian cows from organic farm

The aim of the study was to determine concentration of macroelements (P, Ca, Mg, Na, K), and some microelements, including toxic heavy metals (Cr, Fe, Mn, Zn, Cu, Co, Pb, Cd and Hg) in milk of Jersey cows. Milk samples were collected from Jersey cows kept in tie-stall barn in Greater Poland Province. The feeding was based on total mixed ration mixture. The maximum permitted level of Pb concentration in raw milk (0.02 mg/kg wet weight)was significantly exceeded (0.063±0.035 mg/dm3). The content of Hg was very low (0.106±0.057 μg/dm3).Significant (P£0.05) Spearman coefficient correlations were observed between contents of some elements in milk. Especially interesting were positive correlations of heavy metals: Cd-Cr, Co-Mn, Cr-Zn, Mn-Zn. Additionally the content of Ca was positively correlated with numerous elements: Hg, Cr, Cu, Mn, Zn, Mg, and negatively correlated with the content of Fe.

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Estimation the Presence of Heavy Metals and Trace Elements in Indian Herbal Cosmetics by Atomic Absorption Spectrophotometer

Asian Journal of Pharmaceutical Research and Development ◽

10.22270/ajprd.v7i5.556 ◽

1970 ◽

Vol 7 (5) ◽

pp. 59-64

Author(s):

Krishnasis Chakraborty ◽

Suraj Chaudhary

Keyword(s):

Heavy Metals ◽

Trace Elements ◽

Atomic Absorption Spectrometry ◽

Atomic Absorption ◽

Absorption Spectrometry ◽

Permissible Limit ◽

Toxic Heavy Metals ◽

Herbal Cosmetics ◽

Cu And Zn ◽

Metals And Trace Elements

Heavy metals are identically Pb, Cd and micronutrients elements like Ca, Mg, Al, Cu and Zn were quantitatively estimated using Flame Atomic Absorption Spectrometry (FAAS). Similarly, heavy metals such as As and Hg were quantitatively estimated by Hydride Generation Technique i.e. Cold Vapor Atomic Absorption Spectrometry method expending nitrogen as carrier gas in 30 herbal cosmetic preparations available in Indian markets. The results designate that among the toxic heavy metals. In the present study, Arsenic was found significantly well below the permissible limit, but Cd was found above the permissible limit in the all samples. Trace elements like Ca and Mg were found in higher amount than compare to Al, Cu, and Zn. Presence of trace elements can corroborate to be beneficial but existence of toxic heavy metals in such amounts certainly has adverse effects on the consumer health who always take the herbal products in an impression of being safe because of the natural origin. In conclusion, execution of strict and isolated regulatory guidelines and promotion of Good Analytical Practice (GAP), Good Manufacturing Practices (GMP) and Good Agricultural and Control Practices (GACP) is suggested for herbal cosmetics by WHO and other regulatory agencies. This study presents the status of heavy metals and trace elements in marketed herbal cosmetic formulations and provides a simple and convenient AAS method which can effectively be adopted at Industrial level for the quality control and standardization of herbal cosmetic preparations and other related products.

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