Synthesis of Ag-incorporated TiO2 nanoparticles by simple green approach as working electrode for dye-sensitized solar cells

Author(s):  
S. Rajkumar ◽  
M. R. Venkatraman ◽  
K. Suguna ◽  
P. Karuppasamy ◽  
M. Senthil Pandian ◽  
...  
Energies ◽  
2018 ◽  
Vol 11 (11) ◽  
pp. 2922 ◽  
Author(s):  
Zainal Arifin ◽  
Suyitno Suyitno ◽  
Syamsul Hadi ◽  
Bayu Sutanto

In this study, dye-sensitized solar cells (DSSCs) were fabricated using double-layer photoanodes consisting of TiO2 nanoparticles (NPs) and Zn-doped TiO2 hollow fibers (HFs). The TiO2 HFs were prepared by co-axial electrospinning and used as the light-scattering layer in the DSSC. The thickness variations of the TiO2 NP and Zn-doped TiO2 HF photoanode layers affect the performance of the DSSC, especially the short-circuit photocurrent density. The thickness of the TiO2 NP layer significantly affected the absorbance of photons and N719 dye molecules in the double-layer photoanode, while that of the Zn-doped TiO2 HF layer affected the scattering of light, as indicated by the low light transmittance in the photoanode. Conventional DSSCs consist of single-layer photoanodes, and exhibit relatively low efficiency, i.e., 1.293% and 0.89% for TiO2 NP and Zn-doped TiO2 HF, respectively. However, herein, the highest efficiency of the DSSC (3.122%) was achieved with a 15 μm NP-5 μm HF photoanode, for which the short-circuit photocurrent density, open-circuit photovoltage, and fill factor were 15.81 mA/cm2, 0.566 V, and 34.91%, respectively.


2017 ◽  
Vol 43 (8) ◽  
pp. 4339-4352 ◽  
Author(s):  
Orawan Wiranwetchayan ◽  
Wonchai Promnopas ◽  
Supab Choopun ◽  
Pisith Singjai ◽  
Somchai Thongtem

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