Synthesis and Crystal Structures of the Mixed Ligand Coordination Polymers [Co2(N3)2(BZA)4(H2O)]·EtOH, Cu(N3)(BZA)2(H2O), and Cu(N3)(SUCC)(H2O)2 (N3 = 1,4-bis(3-pyridyl)-2,3-diaza-1,3-butadiene, BZA = benzoate, and SUCC = succinate)

2011 ◽  
Vol 42 (2) ◽  
pp. 141-149 ◽  
Author(s):  
Rachel C. Severance ◽  
Mark D. Smith ◽  
Shae Anne Vaughn ◽  
LeRoy Peterson ◽  
Hans-Conrad zur Loye
Keyword(s):  
Crystal Structures ◽  
Coordination Polymers ◽  
Mixed Ligand ◽  
Ligand Coordination

Crystal structures, topological analysis and luminescence properties of three coordination polymers based on a semi-rigid ligand and N-donor ligand linkers

2016 ◽  
Vol 40 (7) ◽  
pp. 5957-5965 ◽  
Author(s):  
Xiaobin Liu ◽  
Zhenyu Xiao ◽  
Ao Huang ◽  
Wen Wang ◽  
Liangliang Zhang ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Coordination Polymers ◽  
Topological Analysis ◽  
Mixed Ligand ◽  
Donor Ligands ◽  
Luminescence Properties ◽  
Donor Ligand ◽  
Ligand Coordination

Three new mixed-ligand coordination polymers have been synthesized based on 3,3′-(anthracene-9,10-diyl)diacrylate acid and different N-donor ligands. Complex 2 displays rapid and selective sensing of Fe3+.

scholarly journals Two mixed-ligand coordination polymers based on 2,5-thiophenedicarboxylic acid and flexible N-donor ligands: the protective effect on periodontitis via reducing the release of IL-1β and TNF-α

2020 ◽  
Vol 18 (1) ◽  
pp. 391-398
Author(s):  
Shao-Hsuan Wu ◽  
Jun-Hui Huang
Keyword(s):  
Coordination Polymers ◽  
Gingival Crevicular Fluid ◽  
Mixed Ligand ◽  
Donor Ligands ◽  
X Ray Diffraction ◽  
Functional Studies ◽  
Tnf Α ◽  
Mucosal Cells ◽  
Ligand Coordination ◽  
Crevicular Fluid

AbstractTwo novel mixed-ligand coordination polymers, {[Co(tdc)(btrp)]·0.67DMF}n (1) and {[Zn2(bimb)2(tdc)2]·2H2O}n (2) involving 2,5-thiophenedicarboxylate (H2tdc), and bitopic flexible N-donor ligands, 1,3-bis(1,2,4-triazol-1-yl)propane (btrp) and 1,4-bis((1H-benzo[d]imidazol-1-yl)methyl)benzene (bimb), have been synthesized by the hydrothermal method and characterized via IR, elemental analysis, thermal analysis, and powder X-ray diffraction. The biological functional studies were performed; the treatment activity of the compounds on periodontitis and the specific mechanism was explored. First, the real-time RT-PCR was carried out to determine the inflammatory genes nf-κb and p53 relative expression in periodontal mucosal cells after treating with compounds 1 and 2. Then, the level of the inflammatory cytokine in the gingival crevicular fluid after treating with compounds was also determined by the ELISA detection kit.

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