Effect of Solvent on Third-Order Nonlinear Optical Behavior of Reactive Blue 19 Dye

Author(s):  
S. Jeyaram ◽  
J. Naseer ◽  
S. Punitha
Ionics ◽  
2016 ◽  
Vol 23 (2) ◽  
pp. 343-346 ◽  
Author(s):  
A. Karakas ◽  
M. Karakaya ◽  
M. Taser ◽  
Y. Ceylan ◽  
A.K. Arof ◽  
...  

2018 ◽  
Vol 32 (31) ◽  
pp. 1850351 ◽  
Author(s):  
S. Karuna ◽  
A. R. Balu ◽  
D. Shyamala ◽  
V. S. Nagarethinam ◽  
Z. Delci

A third-order nonlinear optical crystal of lithium hydrogen maleate dihydrate (LHMD) is grown by the process of slow evaporation at room-temperature. The LHMD crystal system is orthorhombic and is a member of P space group. Using FTIR spectral investigation, the presence of main functional groups in LHMD crystal is identified. The optical behavior of the crystal is determined by UV-Visible spectroscopy. The bandgap energy of the LHMD crystal is calculated to be 3.4 eV. By Vickers microhardness measurements, the mechanical behavior has been assessed. The melting point of LHMD is determined by TG-DTA analysis. The defects present in the LHMD crystal are studied by dielectric loss and dielectric constant. SHG studies are performed for the LHMD crystal by Kurtz and Perry method. The third-order nonlinear characteristics of the LHMD crystal are analyzed by Z-scan technique. The laser damage threshold (LDT) study is carried out to verify the suitability of the crystal for laser applications.


2008 ◽  
Vol 63 (11) ◽  
pp. 1315-1320
Author(s):  
Hüseyin Üver ◽  
Aslı Karaka§ ◽  
Ayhan Elmalı ◽  
T. Nuri Durlu

Abstract N-(2-hydroxy-4-methoxybenzylidene)-3-nitroaniline (1) has been synthesized and characterized by X-ray diffraction analysis, FTIR and 1H NMR spectroscopy. The maximum one-photon absorption (OPA) wavelengths recorded by quantum mechanical computations using a configuration interaction (CI) method are estimated in the UV region to be shorter than 450 nm, showing good optical transparency to the visible light. We have computed both dispersion-free (static) and also frequency-dependent (dynamic) linear polarizabilities (α) and second hyperpolarizabilities (γ) by using the time-dependent Hartree-Fock (TDHF) method to provide an insight into the microscopic third-order nonlinear optical (NLO) behavior of the title compound. The ab initio calculation results with non-zero values on (hyper)polarizabilities indicate that the synthesized molecule might possess microscopic third-order NLO phenomena.


2022 ◽  
Vol 124 ◽  
pp. 111950
Author(s):  
T. Sofia Nirmala ◽  
N. Iyandurai ◽  
S. Yuvaraj ◽  
M. Sundararajan

2017 ◽  
Vol 35 (2) ◽  
pp. 313-321 ◽  
Author(s):  
M. Krishnakumar ◽  
K. Thirupugalmani ◽  
S. Brahadeeswaran

Abstract Optically transparent single crystals of 2-amino-5-chloropyridinium-4-amino benzoate (2A5CP4AB) were grown at room temperature using solution growth technique. The structure was solved with a support of single crystal XRD, which revealed that the title compound belongs to the monoclinic crystal system having centrosymmetric space group P21/n. The UV-Vis spectrum and photoluminescence properties of the title compound showed the optical transmittance and emission behavior of the compound. The optical band gap was evaluated using the Tauc plot and it was found to be about 3.53 eV. The third order nonlinear optical behavior of the crystal was determined using Z-scan technique. Mechanical properties of the title compound were studied using Vickers microhardness study.


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