Does Entrepreneur Moral Reflectiveness Matter? Pursing Low-Carbon Emission Behavior among SMEs through the Relationship between Environmental Factors, Entrepreneur Personal Concept, and Outcome Expectations

The intensity and severe impact of carbon emissions on the environment has been witnessed globally. This study aims to unravel how environmental factors, personal factors, and entrepreneur outcome expectations affect entrepreneur low-carbon emission behavior (LCB) through the lens of social cognitive theory (SCT). To achieve the aims of this study, we gathered data from 1015 entrepreneurs and small, medium-sized enterprises (SMEs) in the Jiangsu province of China to analyze the predictors of entrepreneur low-carbon behavior. The proposed relationships were tested using the partial least square structural equation modelling (PLS-SEM) technique. The findings from the study indicate that environmental factors (i.e., climate change (CC), public media (PM), and corporate social responsibility (CSR) have a significant and positive relationship with entrepreneur LCB. Moreover, entrepreneur green production self-efficacy (GPS) is positively associated with entrepreneur LCB. The findings further revealed that entrepreneur personal concepts such as entrepreneur self-monitoring (SM), entrepreneur self-esteem (SE), and entrepreneur self-Preference (SP) significantly and completely affect entrepreneur GPS. Likewise, entrepreneur moral reflectiveness (EMR) substantially moderates the relationship between entrepreneur green production outcome expectation and LCB. This study concludes with recommendations for researchers interested in enhancing knowledge in this field. In summation, this study shows that a behavioral science viewpoint is critical for improving knowledge of low-carbon environment, CC drivers, mitigation strategies, and sustainable transition to our complex environment.

Strong coupling in two-dimensional materials-based nanostructures: a review

Strong interaction between electromagnetic radiation and matter leads to the formation of hybrid light-matter states, making the absorption and emission behavior different from those of the uncoupled states. Strong coupling effect results in the famous Rabi splitting and the emergence of new polaritonic eigenmodes, exhibiting spectral anticrossing behavior and unique energy-transfer properties. In recent years, there has been a rapidly increasing number of works focusing on strong coupling between nanostructures and two-dimensional materials (2DMs), because of the exceptional properties and applications they demonstrate. Here, we review the significant recent advances and important developments of strong light-matter interactions in 2DMs-based nanostructures. We adopt the coupled oscillator model to describe the strong coupling and give an overview of various hybrid nanostructures to realize this regime, including graphene-based nanostructures, black phosphorus-based nanostructures, transition-metal dichalcogenides-based nanostructures, etc. In addition, we discuss potential applications that can benefit from these effects and conclude our review with a perspective on the future of this rapidly emerging field.

Poly(ʟ-lactide)s with Tetraphenylethylene: Role of Polymer Chain Packing on Aggregation-Induced Emission Behavior of Tetraphenylethylene

Development of biocompatible and biodegradable fluorescent polymers and understanding their fluorescent characteristics are highly desirable. In this work, we synthesized one-armed, two-armed and four-armed poly(ʟ-lactide)s by ring-opening polymerization of ʟ-lactide...

On Modelling Approaches to the Influence of Mechanical Deformation on the Micromagnetic Activity in a Mild Steel

In this study an attempt is made to develop a theoretical modelling by which the influence of certain mechanical deformation factors on the micromagnetic emission behavior of a low-carbon steel can reasonably be described and estimated. This modelling consists of a simple kinetics – kinematics – aided approach of the pinning state – controlled domain wall motion by which appropriate specific parameters are introduced. In this aspect the basic notion of specific micromagnetic activity (s.m.a.) is introduced by which the energetic strength of the activity is reflected. In this way, the synergetic effect of the quantitative (count rate) and qualitative (voltage) the detected micromagnetic Barkhausen emission (MBE) is taken into consideration. Thus it is possible, theoretically, to give a prediction of the general trend of changes in the s.m.a. under the influence of the tensile elastic as well as plastic deformation. For instance, one can demonstrate that tensile elastic deformation cannot influence the s.m.a. whereas plastic one leads to an increase in this. Furthermore, one can also predict that increasing permanent (residual) plastic deformation, obtained after unloading from prior tensile loading, leads to an obvious decrease in the s.m.a. Similar decrease in the s.m.a. can also be predicted for increasing rolling deformation by means of the same modelling approach used for the permanent tensile plastic deformation. Owing to the good agreement with the experimental results and the simplicity of the proposed theoretical approaches that can be seen as a promising valuable tool for further similar studies.

Regioisomeric Effect on the Excited-State Fate Leading to Room-Temperature Phosphorescence or Thermally Activated Delayed Fluorescence in a Dibenzophenazine-Cored Donor–Acceptor–Donor System

Exploring design principle for switching thermally activated dealyed fluorescecne (TADF) and room temperature phosphorescence (RTP) is a fundamentally imporant research in developing triplet-mediated photofunctional organic materials. Herein systematic studies on the regioisomeric and substituents effects in a twisted donor–acceptor–donor (D–A–D) scaffold (A = dibenzo[a,j]phenazine; D = dihydrophenazasiline) on the fate of the excited state have been performed. The study revealed that the regiosiomerism clearly affects the emission behavior of the D–A–D compounds. Distinct difference in TADF, dual TADF & RTP, and dual RTP were observed, depending on the host used. Furthermore, OLED organic light-emitting diodes (OLEDs) fabricated with the developed emitters achieved high external quantum yields for RTP-based OLEDS up to 7.4%.

Mononuclear Copper(I) 3-(2-pyridyl)pyrazole Complexes: The Crucial Role of Phosphine on Photoluminescence

A series of emissive Cu(I) cationic complexes with 3-(2-pyridyl)-5-phenyl-pyrazole and various phosphines: dppbz (1), Xantphos (2), DPEPhos (3), PPh3 (4), and BINAP (5) were designed and characterized. Complexes obtained exhibit bright yellow-green emission (ca. 520–650 nm) in the solid state with a wide range of QYs (1–78%) and lifetimes (19–119 µs) at 298 K. The photoluminescence efficiency dramatically depends on the phosphine ligand type. The theoretical calculations of buried volumes and excited states explained the emission behavior for 1–5 as well as their lifetimes. The bulky and rigid phosphines promote emission efficiency through the stabilization of singlet and triplet excited states.

Performance and Emission Analysis of Waste Animal Fat Methyl Esters Blends on Naturally Aspirated Single Cylinder Engine

With emergent energy demands along growing concerns over health and ecological issues, have motivated consideration of biomasses derived alternative fuels, such as biodiesel for IC engines. In the current study transesterified waste animal fat was investigated for performance and emission characteristics and compared with mineral diesel. Experiments was performed on a single cylinder four stroke CI engine with constant injection pressure on Kirloskar TV1 having power 3.60 kW @ 1500 rpm. Using these constraints BTE and BSEC are computed. Exhaust emission behavior of such alternative fuels is vital in order to assess suitability for further utilization to compare these uHC, CO, NOx and smoke emission were also measured for all the test fuels. Emission reports indicate higher NOx and lesser CO emissions compared to mineral diesel. The characteristics found to be equivalent with ASTM Standards which is a favorable fuel requirement.

Electrochemical and Fluorescent Properties of Crown Ether Functionalized Graphene Quantum Dots for Potassium and Sodium Ions Detection

The concentration of sodium and potassium ions in biological fluids, such as blood, urine and sweat, is indicative of several basic body function conditions. Therefore, the development of simple methods able to detect these alkaline ions is of outmost importance. In this study, we explored the electrochemical and optical properties of graphene quantum dots (GQDs) combined with the selective chelating ability of the crown ethers 15-crown-5 and 18-crown-6, with the final aim to propose novel composites for the effective detection of these ions. The results obtained comparing the performances of the single GQDs and crown ethers with those of the GQDs-15-crown-5 and GQDs-18-crown-6 composites, have demonstrated the superior properties of these latter. Electrochemical investigation showed that the GQDs based composites can be exploited for the potentiometric detection of Na+ and K+ ions, but selectivity still remains a concern. The nanocomposites showed the characteristic fluorescence emissions of GQDs and crown ethers. The GQDs-18-crown-6 composite exhibited ratiometric fluorescence emission behavior with the variation of K+ concentration, demonstrating its promising properties for the development of a selective fluorescent method for potassium determination.