Synthesis, mechanical properties and enzymatic degradation of biodegradable poly(butylene carbonate-co-terephthalate)/organically modified layered double hydroxide nanocomposites

Author(s):  
Ming-Cheng Hsu ◽  
Jie-Mao Wang ◽  
Tzong-Ming Wu
2019 ◽  
Vol 27 (5) ◽  
pp. 287-298
Author(s):  
Xincheng Guo ◽  
Mengqi Tang ◽  
Na Wang ◽  
Lingtong Li ◽  
Yifan Wu ◽  
...  

Organically modified layered double hydroxide (OM-LDH) was synthesized via anion exchange reaction and potassium monolauryl phosphate (MAPK) was used as an intercalator. The OM-LDH nanofillers were embedded into low-density polyethylene/ethylene–vinyl acetate (LDPE/EVA) via melt blending process which provided LDPE/EVA/OM-LDH nanocomposites. The structure and properties of the fabricated samples were characterized through Fourier transform infrared spectroscopy, X-ray diffraction techniques, scanning electron microscopy, thermogravimetric analysis, differential scanning calorimetry, and tensile testing. The results showed that the organic anion was intercalated into the interlayer region of LDH and enlarged the interlayer distance. The TGA results of the nanocomposites showed significantly improved thermal stability at a higher temperature when containing 6 wt% OM-LDH due to the good dispersion of OM-LDH in the matrix. The DSC data indicated that the degree of crystallinity was increased obviously due to the incorporation of OM-LDH in the matrix. The formation of organic side chains on the OM-LDH surface also contributed to an improvement in the interfacial adhesion, resulting in enhanced tensile strength and elongation at break compared with LDH.


2020 ◽  
Vol 137 (27) ◽  
pp. 48894 ◽  
Author(s):  
Monika Singh ◽  
Divya Somvanshi ◽  
Rajesh K. Singh ◽  
Arun K. Mahanta ◽  
Pralay Maiti ◽  
...  

2017 ◽  
Vol 42 (2) ◽  
pp. 213-220 ◽  
Author(s):  
Ehsan Naderi Kalali ◽  
Anabel Montes ◽  
Xin Wang ◽  
Lu Zhang ◽  
Marjan E. Shabestari ◽  
...  

2014 ◽  
Vol 71 (9) ◽  
pp. 2235-2245 ◽  
Author(s):  
Núria Angelo Gonçalves ◽  
Telma Regina Nogueira Caio ◽  
Samara Boaventura de Moraes ◽  
Liliane Maria Ferrareso Lona

2015 ◽  
Vol 3 (45) ◽  
pp. 22730-22738 ◽  
Author(s):  
Jae-Hun Yang ◽  
Wei Zhang ◽  
Hyunju Ryu ◽  
Ji-Hee Lee ◽  
Dae-Hwan Park ◽  
...  

The thermal stability of PP was significantly improved after the formation of PP nanocomposites with organo-LDH, which was affected by the type of organic modifier in organo-LDH and the loading amount of organo-LDH.


Sign in / Sign up

Export Citation Format

Share Document