Kinetics and Mechanism of High-Temperature Oxidation in Air of Au - Cu Alloy

2005 ◽  
Vol 44 (7-8) ◽  
pp. 377-381 ◽  
Author(s):  
V. A. Lavrenko ◽  
L. I. Kuznetsova ◽  
A. I. Malyshevskaya
2021 ◽  
pp. 163007
Author(s):  
Zi J. Zhao ◽  
Wan P. Li ◽  
Yen H. Chen ◽  
Xin Y. Liu ◽  
Zi X. Zhou ◽  
...  

2010 ◽  
Vol 65 ◽  
pp. 106-111
Author(s):  
Bai Cui ◽  
Rafael Sa ◽  
Daniel Doni Jayaseelan ◽  
Fawad Inam ◽  
Michael J. Reece ◽  
...  

Microstructural evolution of Ti2AlN ceramics during high-temperature oxidation in air has been revealed by X-ray diffraction (XRD), field emission gun scanning electron microscopy (FEGSEM), and energy-dispersive spectroscopy (EDS). After oxidation below 1200 °C, layered microstructures formed on Ti2AlN surfaces containing anatase, rutile, and α-Al2O3. Above 1200 °C, more complex layered microstructures formed containing Al2TiO5, rutile, α-Al2O3, and continuous void layers. With increasing temperature, anatase gradually transformed to rutile, and TiO2 reacted with α-Al2O3 to form Al2TiO5. Based on these microstructural observations, an oxidation mechanism for Ti2AlN ceramics is proposed.


2015 ◽  
Vol 465 ◽  
pp. 400-406 ◽  
Author(s):  
А.S. Kuprin ◽  
V.А. Belous ◽  
V.N. Voyevodin ◽  
V.V. Bryk ◽  
R.L. Vasilenko ◽  
...  

2019 ◽  
Vol 45 (5) ◽  
pp. 6392-6404 ◽  
Author(s):  
A.N. Astapov ◽  
Yu.S. Pogozhev ◽  
M.V. Prokofiev ◽  
I.P. Lifanov ◽  
A.Yu. Potanin ◽  
...  

2019 ◽  
Vol 944 ◽  
pp. 110-119 ◽  
Author(s):  
Hang Chen ◽  
Guang Bao Mi ◽  
Pei Jie Li ◽  
Chun Xiao Cao

The oxidation behavior and mechanism of Ti-Cu alloys (0≤w(Cu)≤20%) in the temperature range of 1000°C~1300°C are studied by thermogravimetric analysis(TGA) combined with SEM, EDS and XRD analysis methods. The results show that the oxidation rates of Ti-Cu alloys increase sharply when the temperature rises above 1000°C. The oxidation products have a three-layer structure, from the outside to the inside, which are dense outer oxide layer of TiO2, porous inner oxide layer of low valence oxide of Ti and Cu-enriched layer. With the increase of the temperature, the thicknesses of oxide layers of Ti-Cu alloy increase and the Cu-enriched phase increases gradually and melts. The melting Cu-enriched phase flows to the oxidation surface along the grain boundaries of the oxide layer. The high temperature oxidation resistance of Ti-Cu alloys declines with the increase of Cu content. The main reason is that more liquid Cu-enriched phase is formed and flows to the oxidation surface along the oxide grain boundaries in the Ti-Cu alloy, and Ti and O ions can diffuse more easily along the liquid Cu-enriched phase, which increases the oxidation rates.


2006 ◽  
Vol 45 (9-10) ◽  
pp. 476-480 ◽  
Author(s):  
V. A. Lavrenko ◽  
A. I. Malyshevskaya ◽  
L. I. Kuznetsova ◽  
V. F. Litvinenko ◽  
V. N. Pavlikov

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