Catalytic performance of polymer-supported ionic liquids in the cycloaddition of carbon dioxide to allyl glycidyl ether

Six new air-stable anionic platinum complexes were synthesized in simple reactions of piperidinium [BMPip]Cl or pyrrolidinium [BMPyrr]Cl ionic liquids with platinum compounds ([Pt(cod)Cl2] or K2[PtCl6]). All these compounds were subjected to isolation and spectrometric characterization using NMR and ESI-MS techniques. Furthermore, the determination of melting points and thermal stability of the above derivatives was performed with the use of thermogravimetric analysis. The catalytic performance of the synthesized complexes was tested in hydrosilylation of 1-octene and allyl glycidyl ether with 1,1,1,3,5,5,5-heptamethyltrisiloxane. The study has shown that they have high catalytic activity and are insoluble in the reaction medium which enabled them to isolate and reuse them in consecutive catalytic cycles. The most active complex [BMPip]2[PtCl6] makes it possible to conduct at least 10 catalytic runs without losing activity which makes it an attractive alternative not only to commonly used homogeneous catalysts, but also to heterogeneous catalysts for hydrosilylation processes. The activity of the studied catalysts is also affected by the kind of anion and, to some extent, the kind of cation.

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Addition of carbon dioxide to allyl glycidyl ether using ionic liquids catalysts

Catalysis Today ◽

10.1016/j.cattod.2006.02.054 ◽

2006 ◽

Vol 115 (1-4) ◽

pp. 130-133 ◽

Cited By ~ 37

Author(s):

Dae-Won Park ◽

Na-Young Mun ◽

Kyung-Hoon Kim ◽

Il Kim ◽

Sang-Wook Park

Keyword(s):

Carbon Dioxide ◽

Ionic Liquids ◽

Glycidyl Ether ◽

Allyl Glycidyl Ether

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Effect of anion type of imidazolium based polymer supported ionic liquids on the solvent free synthesis of cycloaddition of CO2 into epoxide

Catalysis Today ◽

10.1016/j.cattod.2015.09.048 ◽

2016 ◽

Vol 265 ◽

pp. 56-67 ◽

Cited By ~ 54

Author(s):

Arvind H. Jadhav ◽

Gaurav M. Thorat ◽

Kyuyoung Lee ◽

Alan Christian Lim ◽

Hyo Kang ◽

...

Keyword(s):

Ionic Liquids ◽

Solvent Free ◽

Polymer Supported ◽

Supported Ionic Liquids ◽

Solvent Free Synthesis ◽

Anion Type

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Catalytic performance of a series of guanidinium-based ionic liquids in the coupling reaction of carbon dioxide with epoxides

RSC Advances ◽

10.1039/c6ra20174a ◽

2016 ◽

Vol 6 (90) ◽

pp. 87036-87043 ◽

Cited By ~ 9

Author(s):

Ping Li ◽

Ya Li ◽

Ci Chen ◽

Li Wang ◽

Jinglai Zhang

Keyword(s):

Carbon Dioxide ◽

Ionic Liquids ◽

Cycloaddition Reaction ◽

Coupling Reaction ◽

Catalytic Performance

The cycloaddition reaction of CO2 into EO, catalyzed by a series of functional guanidinium-based ionic liquids, is schematically studied by the DFT.

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Multilayered supported ionic liquids bearing a carboxyl group: Highly efficient catalysts for chemical fixation of carbon dioxide

Journal of Environmental Chemical Engineering ◽

10.1016/j.jece.2016.05.001 ◽

2016 ◽

Vol 4 (2) ◽

pp. 2565-2572 ◽

Cited By ~ 9

Author(s):

Xu Zhang ◽

Wenhao Geng ◽

Chengtao Yue ◽

Wei Wu ◽

Linfei Xiao

Keyword(s):

Carbon Dioxide ◽

Ionic Liquids ◽

Carboxyl Group ◽

Chemical Fixation ◽

Highly Efficient ◽

Supported Ionic Liquids ◽

Fixation Of Carbon Dioxide

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Highly recyclable polymer supported ionic liquids as efficient heterogeneous catalysts for batch and flow conversion of CO2 to cyclic carbonates

RSC Advances ◽

10.1039/c6ra26780g ◽

2017 ◽

Vol 7 (5) ◽

pp. 2836-2841 ◽

Cited By ~ 24

Author(s):

Tao Wang ◽

Wenlong Wang ◽

Yuan Lyu ◽

Xingkun Chen ◽

Cunyao Li ◽

...

Keyword(s):

Ionic Liquids ◽

Radical Polymerization ◽

Quaternary Ammonium ◽

Heterogeneous Catalysts ◽

Quaternary Ammonium Salts ◽

Ammonium Salts ◽

Cyclic Carbonates ◽

Polymer Supported ◽

Supported Ionic Liquids

A series of cross-linked polymer supported ionic liquids based on quaternary ammonium salts have been prepared using a facile method of radical polymerization.

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