scholarly journals Geochemical distribution of major and trace elements in agricultural soils of Castilla-La Mancha (central Spain): finding criteria for baselines and delimiting regional anomalies

2017 ◽  
Vol 26 (4) ◽  
pp. 3100-3114 ◽  
Author(s):  
Sandra Bravo ◽  
Efrén García-Ordiales ◽  
Francisco Jesús García-Navarro ◽  
José Ángel Amorós ◽  
Caridad Pérez-de-los-Reyes ◽  
...  
2015 ◽  
Vol 2015 ◽  
pp. 1-10 ◽  
Author(s):  
Sandra Bravo Martín-Consuegra ◽  
Jose A. Amorós Ortíz-Villajos ◽  
Caridad Pérez-de-los-Reyes ◽  
Francisco J. García Navarro ◽  
Rolando Ruedas Luna ◽  
...  

The study of five soil profiles developed on carbonatic sediments of Tertiary Miocene origin has been carried out. The topography of the area was basically flat and the traditional uses of the soils are the cultivation of dry cereals and grapevine. The geochemical characterization of the aforementioned profiles involves a study of the contents of major and trace elements among other pedologic aspects (texture, pH, organic matter, etc.). The results of this study also indicate a superficial enrichment of trace elements due to the leaching of Ca and moderate biological and anthropic activity. We can consider strontium, Sr, as the trace element that characterizes these limy soils (435 mg/kg average content in total soil and 708 mg/kg in the original rock). These contents are similar to the average value in Castilla-La Mancha of 380 mg/kg and are higher than the average in world soils of about 200 mg/kg. High levels of dangerous or pollutant elements (Cd, Hg, Pb, Cu, Zn, or Ni) were not detected. The majority of trace element anomalies are related to calcareous material and the leaching of calcium carbonate (Ca), while the influence of the anthropogenic factor is secondary. Soil quality does not indicate toxicity although surficial enrichment suggests a weak threat from consuming crops.


Author(s):  
RAIMUNDO JIMENEZ-BALLESTA ◽  
Sandra Bravo ◽  
Caridad Pérez de los Reyes ◽  
JOSE A. AMOROS ◽  
Jesus Garcia-Pradas ◽  
...  

The study reported here concerns the geochemical distributions of macro- and trace elements (including potentially toxic elements, PTEs) in the vineyard soils of Alcubillas, which is one of the oldest, albeit not world-reknowned, wine-growing areas in La Mancha (Central Spain). Soil and leaf samples were analyzed by X-ray fluorescence spectrometry to ascertain the levels of various elements in the soil and the plant. The potential toxicity of the elements was assessed with regard to the development of the vineyard. Despite the fact that fertilizers and pesticides are employed in the vineyards in this area, the results showed that the levels of trace elements in the soil samples did not exceed the reference values according the pedogeochemical values for the region and Spain. This finding suggests that the study area is not polluted. The Biological Absortion Coefficient (BAC) was calculated to assess the assimilation of various elements from the soil to the leaves, and differences were found in the element absorption capacity of the vines. Some elements were not taken up by Vitis vinifera despite elements like Zr and Rb being present in relatively high concentrations in the soil. The production in these soils of grapes and wine does not represent a threat to human health or the ecosystem, because the farmers in this area are extremely careful to preserve the environment and they only farm to achieve moderate yields of grapes per hectare.


2022 ◽  
Vol 233 (1) ◽  
Author(s):  
R. Jiménez-Ballesta ◽  
S. Bravo ◽  
J. A. Amorós ◽  
C. Pérez-de-los-Reyes ◽  
J. García-Pradas ◽  
...  

Abstract The study reported here concerns the geochemical distributions of macro- and trace elements (including potentially toxic elements, PTEs) in the vineyard soils of Alcubillas, which is one of the oldest, albeit not world-renowned, wine-growing areas in La Mancha (Central Spain). Soil and leaf samples were analyzed by X-ray fluorescence spectrometry to ascertain the levels of various elements in the soil and the plant. The potential toxicity of the elements was assessed with regard to the development of the vineyard. Despite the fact that fertilizers and pesticides are employed in the vineyards in this area, the results showed that the levels of trace elements in the soil samples did not exceed the reference values according the pedogeochemical values for the region and Spain. This finding suggests that the study area is not polluted, and therefore, there are hardly any traces of anthropogenic contamination. The Biological Absorption Coefficient (BAC) was calculated to assess the assimilation of various elements from the soil to the leaves, and differences were found in the element absorption capacity of the vines. Some elements were not taken up by Vitis vinifera despite elements like Zr and Rb being present in relatively high concentrations in the soil. The production in these soils does not represent a threat to human health or the ecosystem, because the farmers in this area are extremely careful to preserve the environment and they only farm to achieve moderate yields of grapes per hectare.


2005 ◽  
Vol 31 (3) ◽  
pp. 313-323 ◽  
Author(s):  
Carlos A. Lucho-Constantino ◽  
Miriam Álvarez-Suárez ◽  
Rosa I. Beltrán-Hernández ◽  
Francisco Prieto-García ◽  
Héctor M. Poggi-Varaldo

Author(s):  
Raimundo Jiménez-Ballesta ◽  
Sandra Bravo ◽  
Jose A. Amorós ◽  
Caridad Pérez-de los Reyes ◽  
Rosario García-Giménez ◽  
...  

The mineralogical and geochemical patterns of calcareous vineyard soils located in Alcubillas (La Mancha, Central Spain) have been evaluated; also their variability has been studied. The information provided by this study supports the assessment of geochemical spatial variability, the origin of these soils, their elements and the factors that control their distribution. The presence of quartz, calcite, feldspar and, in particular, illite and kaolinite is due to their inheritance from surrounding lithologies (and pedological processes), which mostly include limestones, marls and other sedimentary rocks, as well as metasedimentary rocks of Hercynian origin. Furthermore, since the presence and accumulation of certain trace elements in vineyard soils is a relevant global hazard (in particular with respect to wine production quality), the spatial distributions of Ba, Cr, Cu, Pb, Rb, Sr, V and Zr (carried out using geostatistical techniques and geometry-based interpolation methods) were investigated in order to determine the origin of these trace elements. The presence of these elements can be interpreted as being due to geogenic, pedogenic and, in certain cases, anthropic influences. The nature of certain agricultural practices, including the use of fertilizers, phytosanitary products and machinery, could explain the local increases in some trace element contents.


2018 ◽  
Author(s):  
Zoltán Kis ◽  
Katalin Gméling ◽  
Tímea Kocsis ◽  
János Osán ◽  
Mihály András Pocsai ◽  
...  

We present precise analysis of major and trace elements of the humic acid. We used three different element analytical techniques in our investigations as prompt-gamma activation analysis (PGAA), neutron activation analysis (NAA) and X-ray fluorescence (XRF) analysis was carried out. We identified 42 elements in our sample.


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