Influence of different preparation methods on the activity of Ce and Mo co-doped ZSM-5 catalysts for the selective catalytic reduction of NOx by NH3

2020 ◽  
Vol 27 (32) ◽  
pp. 40495-40503
Author(s):  
Zhifang Li ◽  
Jian Yang ◽  
Yadong Zhou ◽  
Jinxing Cui ◽  
Yuanyuan Ma ◽  
...  
Catalysts ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 1034 ◽  
Author(s):  
Caixia Liu ◽  
Huijun Wang ◽  
Ziyin Zhang ◽  
Qingling Liu

The selective catalytic reduction (SCR) has been widely used in industrial denitrification owing to its high denitrification efficiency, low operating costs, and simple operating procedures. However, coal containing a large amount of sulfur will produce SO2 during combustion, which makes the catalyst easy to be deactivated, thus limiting the application of this technology. This review summarizes the latest NH3-SCR reaction mechanisms and the deactivation mechanism of catalyst in SO2-containing flue gas. Some strategies are summarized for enhancing the poison-resistance through modification, improvement of support, the preparation of complex oxide catalyst, optimizing the preparation methods, and acidification. The mechanism of improving sulfur resistance of catalysts at low temperatures is summarized, and the further development of the catalyst is also prospected. This paper could provide a reference and guidance for the development of SO2 resistance of the catalyst at low temperatures.


2015 ◽  
Vol 5 (1) ◽  
pp. 389-396 ◽  
Author(s):  
Zhihua Lian ◽  
Fudong Liu ◽  
Hong He

VOx/CeO2 catalysts prepared by a homogeneous precipitation method exhibited high NOx conversion and strong SO2 resistance in NH3-SCR reaction.


2020 ◽  
Vol 10 (16) ◽  
pp. 5525-5534 ◽  
Author(s):  
Jialiang Gu ◽  
Bingjun Zhu ◽  
Rudi Duan ◽  
Yan Chen ◽  
Shaoxin Wang ◽  
...  

MnOx–FeOx-Loaded silicalite-1 catalysts exhibit high NOx conversion at low temperatures.


RSC Advances ◽  
2020 ◽  
Vol 10 (67) ◽  
pp. 40948-40959
Author(s):  
Caixia Liu ◽  
Huijun Wang ◽  
Yalian Bi ◽  
Ziyin Zhang

The roles of Fe3+ and SO42− are different at low and high temperatures due to their interaction. It is the appropriate contents of Fe3+ and SO42− that can result in high NH3-SCR activity at varying temperatures.


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