A novel ZnO/reduced graphene oxide and Prussian blue modified carbon paste electrode for the sensitive determination of Rutin

2018 ◽  
Vol 62 (2) ◽  
pp. 262-270 ◽  
Author(s):  
Ozma J D’Souza ◽  
Ronald J Mascarenhas ◽  
Ashis K Satpati ◽  
Basavanakote M Basavaraja
2015 ◽  
Vol 39 (5) ◽  
pp. 3875-3881 ◽  
Author(s):  
Hasan Bagheri ◽  
Seyedeh Maryam Arab ◽  
Hosein Khoshsafar ◽  
Abbas Afkhami

Co3O4-reduced graphene oxide acted as a selective and sensitive modifier in a sensing layer for electrochemical determination of atropine.


Sensors ◽  
2021 ◽  
Vol 21 (9) ◽  
pp. 2955
Author(s):  
Josip Radić ◽  
Maša Buljac ◽  
Boštjan Genorio ◽  
Ema Gričar ◽  
Mitja Kolar

A novel promising carbon paste electrode with excellent potentiometric properties was prepared for the analysis of trihexyphenidyl hydrochloride (THP), the acetylcholine receptor and an anticholinergic drug in real samples. It contains 10.2% trihexyphenidy-tetraphenylborate ionic pair as the electroactive material, with the addition of 3.9% reduced graphene oxide and 0.3% of anionic additive into the paste, which consists of 45.0% dibutylphthalate as the solvent mediator and 40.6% graphite. Under the optimized experimental conditions, the electrode showed a Nernstian slope of 58.9 ± 0.2 mV/decade with a regression coefficient of 0.9992. It exhibited high selectivity and reproducibility as well as a fast and linear dynamic response range from 4.0 × 10−7 to 1.0 × 10−2 M. The electrode remained usable for up to 19 days. Analytical applications showed excellent recoveries ranging from 96.8 to 101.7%, LOD was 2.5 × 10−7 M. The electrode was successfully used for THP analysis of pharmaceutical and biological samples.


Sign in / Sign up

Export Citation Format

Share Document