Metalloporphyrin-based covalent organic frameworks composed of the electron donor-acceptor dyads for visible-light-driven selective CO2 reduction

2020 ◽  
Vol 63 (9) ◽  
pp. 1289-1294 ◽  
Author(s):  
Haowei Lv ◽  
Rongjian Sa ◽  
Pengyue Li ◽  
Daqiang Yuan ◽  
Xinchen Wang ◽  
...  
Keyword(s):  
Visible Light ◽  
Electron Donor ◽  
Co2 Reduction ◽  
Covalent Organic Frameworks ◽  
Visible Light Driven ◽  
Donor Acceptor

Visible-light-driven photocatalytic CO2 reduction over ketoenamine-based covalent organic frameworks: role of the host functional groups

2021 ◽  
Author(s):  
Lianlian Peng ◽  
Shuqing Chang ◽  
Ziling Liu ◽  
Yanghe Fu ◽  
Rui Ma ◽  
...  
Keyword(s):  
Visible Light ◽  
Functional Groups ◽  
Charge Separation ◽  
Photocatalytic Performance ◽  
Co2 Reduction ◽  
Covalent Organic Frameworks ◽  
Visible Light Driven ◽  
Photogenerated Charge Separation ◽  
Electron Donating Groups

Compared to the electron-withdrawing groups, the electron-donating groups in TpBD can accelerate the photogenerated charge separation and transfer, thereby improving the photocatalytic performance for photocatalytic CO2 reduction.

Visible Light-Driven α-Alkylation of N-Aryl tetrahydroisoquinolines Initiated by Electron Donor–Acceptor Complexes

2020 ◽  
Vol 22 (18) ◽  
pp. 7290-7294 ◽  
Author(s):  
Qing Xia ◽  
Yufei Li ◽  
Xinmin Wang ◽  
Peng Dai ◽  
Hongping Deng ◽  
...  
Keyword(s):  
Visible Light ◽  
Electron Donor ◽  
Visible Light Driven ◽  
Donor Acceptor

scholarly journals Z-Schematic and visible-light-driven CO2 reduction using H2O as an electron donor by a particulate mixture of a Ru-complex/(CuGa)1−xZn2xS2 hybrid catalyst, BiVO4 and an electron mediator

2018 ◽  
Vol 54 (72) ◽  
pp. 10199-10202 ◽  
Author(s):  
Tomiko M. Suzuki ◽  
Shunya Yoshino ◽  
Tomoaki Takayama ◽  
Akihide Iwase ◽  
Akihiko Kudo ◽  
...  
Keyword(s):  
Visible Light ◽  
Electron Donor ◽  
Aqueous Suspension ◽  
Co2 Reduction ◽  
Metal Sulfide ◽  
Electron Mediator ◽  
Ru Complex ◽  
Particulate Metal ◽  
Visible Light Driven ◽  
Hybrid Photocatalyst

Visible-light-driven Z-schematic CO2 reduction using H2O as an electron donor was achieved by an aqueous suspension of a particulate metal-sulfide/molecular hybrid photocatalyst.

Covalent grafting of molecular photosensitizer and catalyst on MOF-808: effect of pore confinement toward visible light-driven CO2 reduction in water

2021 ◽  
Vol 14 (4) ◽  
pp. 2429-2440
Author(s):  
Sanchita Karmakar ◽  
Soumitra Barman ◽  
Faruk Ahamed Rahimi ◽  
Tapas Kumar Maji
Keyword(s):  
Visible Light ◽  
Aqueous Medium ◽  
Electron Donor ◽  
Co2 Reduction ◽  
Covalent Grafting ◽  
Visible Light Driven ◽  
Natural Photosynthesis

We have fabricated Zr-MBA-Ru/Re-MOFvia post-synthetic modification of MOF-808. The integrated catalyst assembly was used to mimic natural photosynthesis for sunlight-driven CO2 reduction to produce CO in aqueous medium without external sacrificial electron donor.

Visible-Light-Driven Electron Donor–Acceptor Complex Induced Sulfonylation of Diazonium Salts with Sulfinates

2021 ◽  
Author(s):  
Xin Liang ◽  
Yufei Li ◽  
Qing Xia ◽  
Lan Cheng ◽  
Jianbo Guo ◽  
...  
Keyword(s):  
Visible Light ◽  
Electron Donor ◽  
Coupling Reaction ◽  
Diazonium Salts ◽  
Acceptor Complex ◽  
Radical Coupling ◽  
Visible Light Driven ◽  
Donor Acceptor ◽  
Radical Coupling Reaction ◽  
Eda Complex

This work reports an efficient sulfonylation enabled by visible-light-induced radical coupling reaction between phenyl/heterocyclic diazonium salts and sulfinates. Mechanistic experiments disclosed the formation of a versatile electron donor–acceptor (EDA) complex....

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