Experimental Phase Equilibria Studies of the Pb-Fe-O System in Air, in Equilibrium with Metallic Lead and at Intermediate Oxygen Potentials

2017 ◽  
Vol 48 (6) ◽  
pp. 2970-2983 ◽  
Author(s):  
M. Shevchenko ◽  
E. Jak
2011 ◽  
Vol 2011 ◽  
pp. 1-9 ◽  
Author(s):  
Tiziana Fornari ◽  
Daniel Tenllado ◽  
Carlos Torres ◽  
Guillermo Reglero

The Group Contribution Equation of State (GC-EoS) was extended to represent high-pressure phase equilibria behavior of mixtures containing mono-, di-, triglycerides, and carbon dioxide (CO2). For this purpose, the alcohol-ester and the alcohol-triglyceride binary group interaction parameters were regressed in this work, using experimental phase equilibria data from the literature. The capability of the parameters obtained was assessed by applying the GC-EoS model to simulate the supercritical CO2 fractionation of a complex glyceride mixture, which was produced by the ethanolysis of sunflower oil. Experimental data was obtained in a countercurrent packed extraction column at pressures ranging from 16 to 25 MPa and temperatures from 313 to 368 K. The GC-EoS model was applied in a completely predictive manner to simulate the phase equilibria behavior of the multistage separation process. The chemical analysis of the glyceride mixture allowed a significant simplification of its complex composition and thus, a simple and satisfactory simulation of the supercritical extraction process was achieved.


1998 ◽  
Vol 25 (18) ◽  
pp. 3437-3440 ◽  
Author(s):  
J. Barclay ◽  
M. J. Rutherford ◽  
M. R. Carroll ◽  
M. D. Murphy ◽  
J. D. Devine ◽  
...  

2005 ◽  
Vol 81 (9) ◽  
pp. 2493-2496 ◽  
Author(s):  
Ryosuke O. Suzuki ◽  
Jun-ichi Nagata ◽  
Daniel Risold

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