scholarly journals Plasma-Sprayed (Bi2O3)0.705 (Er2O3)0.245 (WO3)0.05 Electrolyte for Intermediate-Temperature Solid Oxide Fuel Cells (IT-SOFCs)

Author(s):  
Rui Chen ◽  
Cheng-Xin Li ◽  
Chang-Jiu Li
2021 ◽  
Author(s):  
Rui Chen ◽  
Cheng-Xin Li ◽  
Chang-Jiu Li

Abstract Stabilized bismuth oxide with fluorite structure is considered a promising electrolyte material for intermediate temperature solid-oxide fuel cells (SOFCs) due to its high oxygen ion conductivity. The ternary system, Bi2O3-Er2O3-WO3, is of particular interest because it is ionically conductive as well as thermally stable. This study investigates the quality of Bi2O3-Er2O3-WO3 (EWSB) electrolyte produced by plasma spraying. The phase structure and cross-sectional microstructure of plasma-sprayed EWSB were characterized by XRD and SEM. The as-sprayed EWSB was found to have a dense microstructure with well bonded lamellae. XRD analysis showed the formation of EWSB with δ-phase and a trace of β-phase, while the β-phase disappeared after annealing at 750°C for 10h. Electrical property tests revealed that the plasma-sprayed electrolyte also had excellent ionic conductivity (0.26 S cm-1 at 750 °C), making it a strong candidate for use in SOFCs at intermediate temperatures.


2012 ◽  
Vol 36 ◽  
pp. 81-87 ◽  
Author(s):  
Chang-sing Hwang ◽  
Chun-Huang Tsai ◽  
Chun-Liang Chang ◽  
Jen-Feng Yu ◽  
Sheng-Hui Nien

2015 ◽  
Vol 3 (14) ◽  
pp. 7535-7553 ◽  
Author(s):  
Shan-Lin Zhang ◽  
Tao Liu ◽  
Chang-Jiu Li ◽  
Shu-Wei Yao ◽  
Cheng-Xin Li ◽  
...  

La0.8Sr0.2Ga0.8Mg0.2O3 (LSGM) is considered a promising electrolyte material for intermediate-temperature solid oxide fuel cells (IT-SOFCs) because of its high ionic conductivity.


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