scholarly journals Thermal decomposition of 1-chloropropane behind the reflected shock waves in the temperature range of 1015–1220 K: Single pulse shock tube and computational studies

2014 ◽  
Vol 126 (4) ◽  
pp. 897-909 ◽  
Author(s):  
G SUDHAKAR ◽  
B RAJAKUMAR
Keyword(s):  
Thermal Decomposition ◽  
Shock Waves ◽  
Shock Tube ◽  
Single Pulse ◽  
Computational Studies ◽  
Temperature Range ◽  
Reflected Shock

Experimental and theoretical study on thermal decomposition of methyl butanoate behind reflected shock waves

RSC Advances ◽  
2015 ◽  
Vol 5 (105) ◽  
pp. 86536-86550 ◽  
Author(s):  
A. Parandaman ◽  
M. Balaganesh ◽  
B. Rajakumar
Keyword(s):  
Thermal Decomposition ◽  
Shock Waves ◽  
Theoretical Study ◽  
Rate Coefficients ◽  
Temperature Range ◽  
Reflected Shock ◽  
Methyl Butanoate

The rate coefficients for total decomposition of MB in the temperature range of 1229–1427 K, were reported.

Mass spectrometric studies of chemical reactions in shock waves: the thermal decomposition of nitrous oxide

1969 ◽  
Vol 47 (4) ◽  
pp. 521-538 ◽  
Author(s):  
S. C. Barton ◽  
J. E. Dove
Keyword(s):  
Thermal Decomposition ◽  
Shock Waves ◽  
Rate Coefficient ◽  
Mass Spectrometric Study ◽  
Mass Spectrometric ◽  
Unimolecular Decomposition ◽  
Reflected Shock ◽  
Secondary Reactions ◽  
Gas Reactions ◽  
Collision Mechanism

Apparatus for the mass spectrometric study of rapid gas reactions in reflected shock waves is described. This apparatus has been applied to the thermal decomposition of 2% N2O in Kr at total gas concentrations of about 1.6 × 10−6 mole cm−3, in the temperature range 1800 to 2800 °K. The principal products of the reaction were found to be N2, O2, NO, and O. The rate coefficient for the unimolecular decomposition of N2O was calculated from the experimental data, and the rates of the secondary reactions between O and N2O were estimated. The possibility of the occurrence of a "weak collision" mechanism in the unimolecular reaction of N2O is discussed.

Shock-initiated exothermic reactions. VI. The oxidation of ethylene oxide and cyclopropane

1969 ◽  
Vol 22 (7) ◽  
pp. 1355 ◽  
Author(s):  
LJ Drummond ◽  
J Kikkert
Keyword(s):  
Shock Waves ◽  
Ethylene Oxide ◽  
Shock Tube ◽  
Induction Period ◽  
Ignition Delay ◽  
Exothermic Reactions ◽  
Induction Periods ◽  
Reflected Shock ◽  
Formaldehyde Oxidation ◽  
Temperature Dependences

Mixtures of ethylene oxide or cyclopropane with oxygen and argon were ignited with reflected shock waves In a shock tube. The temperature dependences of the ignition delay and the growth of light emitted during the induction period to explosion of C2H4O-O2 mixtures indicate that the rate-controlling reaction is that of formaldehyde oxidation. The temperature dependence of induction periods for C3H6-O2 mixtures suggests that a complicated but undetermined mechanism controls the delay to ignition.

Experimental and Modeling Study of the Thermal Decomposition of C3–C5 Ethyl Esters Behind Reflected Shock Waves

2014 ◽  
Vol 118 (10) ◽  
pp. 1785-1798 ◽  
Author(s):  
Wei Ren ◽  
R. Mitchell Spearrin ◽  
David F. Davidson ◽  
Ronald K. Hanson
Keyword(s):  
Thermal Decomposition ◽  
Shock Waves ◽  
Ethyl Esters ◽  
Reflected Shock ◽  
Modeling Study
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