Laser two-photon ionization of aniline in a molecular beam and the bulk gas phase

1979 ◽  
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Author(s):  
John H. Brophy ◽  
Charles T. Rettner
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Youngjee Yoon ◽  
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Bongsoo Kim

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1979 ◽  
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pp. 216-222 ◽  
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Manfred Hofmann ◽  
Samuel Leutwyler ◽  
Ernst Schumacher ◽  
Ludger Wöste

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Zhe Shi ◽  
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1996 ◽  
Vol 252 (3-4) ◽  
pp. 243-247 ◽  
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W. Demtröder

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François Piuzzi ◽  
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Leonid Gorb ◽  
Jerzy Leszczynski

2008 ◽  
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pp. 134310 ◽  
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Doory Kim ◽  
Hyung Min Kim ◽  
Key Young Yang ◽  
Seong Keun Kim ◽  
Nam Joon Kim

Molecules ◽  
2018 ◽  
Vol 23 (11) ◽  
pp. 2836 ◽  
Author(s):  
Sebastian Mai ◽  
Abed Mohamadzade ◽  
Philipp Marquetand ◽  
Leticia González ◽  
Susanne Ullrich

We report time-dependent photoelectron spectra recorded with a single-photon ionization setup and extensive simulations of the same spectra for the excited-state dynamics of 2-thiouracil (2TU) in the gas phase. We find that single-photon ionization produces very similar results as two-photon ionization, showing that the probe process does not have a strong influence on the measured dynamics. The good agreement between the single-photon ionization experiments and the simulations shows that the norms of Dyson orbitals allow for qualitatively describing the ionization probabilities of 2TU. This reasonable performance of Dyson norms is attributed to the particular electronic structure of 2TU, where all important neutral and ionic states involve similar orbital transitions and thus the shape of the Dyson orbitals do not strongly depend on the initial neutral and final ionic state. We argue that similar situations should also occur in other biologically relevant thio-nucleobases, and that the time-resolved photoelectron spectra of these bases could therefore be adequately modeled with the techniques employed here.


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