The effect of magnetic anisotropy on the longitudinal nuclear relaxation time in paramagnetic systems

1990 ◽  
Vol 89 (2) ◽  
pp. 243-254 ◽  
Author(s):  
Ivano Bertini ◽  
Claudio Luchinat ◽  
Kashyap V Vasavada
Physica ◽  
1963 ◽  
Vol 29 (1) ◽  
pp. 50-62 ◽  
Author(s):  
J. Grunzweig ◽  
D. Zamir ◽  
J. Zak

1974 ◽  
Vol 52 (21) ◽  
pp. 3676-3681 ◽  
Author(s):  
Michel Alexandre ◽  
Paul Rigny

Nuclear relaxation time measurements and interpretations of absorption line shape in ClF5 and ClOF3 allow one to complete data for these compounds. Thus, the chemical shift between non-equivalent fluorine atoms in ClOF3 has been found equal to 50 ± 2 p.p.m. The coupling constant, chlorine 35Cl–fluorine is 192 Hz for the axial fluorine, and less than 20 Hz for the equatorial fluorines. In addition to other information, such as exchange times between fluorine atoms in ClOF3, and the mean coupling constant chlorine–fluorine in ClOF3 and ClF3, is reported.


1990 ◽  
Vol 94 (3) ◽  
pp. 342-348 ◽  
Author(s):  
E. W. Lang ◽  
W. Fink ◽  
H. Radkowitsch ◽  
D. Girlich

Physica ◽  
1966 ◽  
Vol 32 (2) ◽  
pp. 433-443 ◽  
Author(s):  
R. Burnett

1988 ◽  
Vol 72 (1-2) ◽  
pp. 165-188 ◽  
Author(s):  
Val�rie Lefevre-Seguin ◽  
Jean Brossel

2017 ◽  
Vol 46 (13) ◽  
pp. 4148-4151 ◽  
Author(s):  
F. Varga ◽  
C. Rajnák ◽  
J. Titiš ◽  
J. Moncoľ ◽  
R. Boča

A bimetallic Co(ii) compound [Co(dppmO,O)3][CoBr4] consisting of cationic octahedral and anionic tetrahedral units shows a sizable magnetic anisotropy and field-supported slow magnetic relaxation with the relaxation time τ = 0.1–0.3 s at T = 1.9 K.


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