Rapid automatic potentiometric method for analytical control in the manufacture of extraction phosphoric acid

Talanta ◽  
1985 ◽  
Vol 32 (10) ◽  
pp. 957-960
Author(s):  
G Velinov
2019 ◽  
Vol 2 ◽  
pp. 11-18
Author(s):  
Smirnov N.N. ◽  
Konoval A.V. ◽  
Smirnova D.N. ◽  
Kochetkov S.P.

The environmental problems of the production of extraction phosphoric acid and the effect of fluorine on the human body are discussed in the article. The creation of the industry of phosphoric fertilizers on the basis of processing of fluorine-containing phosphate raw materials and fluorine-containing compounds, the development of their application require the study of environmental consequences arising from this, because fluorine is characterized by high mobility in the biological cycle of metabolism. For the purification of phosphoric acid from fluorine was used carbon adsorbents such as active charcoal brand BAU, natural graphite deposits Kyshtymsky, P514 soot, charcoal. Experiments on the purification was carried out on non-evaporated half-hydrated extraction phosphoric acid which was produced by joint stock company «Apatit» in Cherepovets city in Russia. The following analyses were carried out: IR-Fourier spectrometry, research of acid–base properties of carbon materials by potentiometric titration, potentiometric method of fluorine determination in extraction phosphoric acid. It is mentioned that the carbon black P514 is the most efficient adsorbent for purification of extraction phosphoric acid. The total number of functional groups on its surface is 0.62 mmol/g, the degree of purification from fluorine compounds is 94.8%.


2021 ◽  
pp. 19-25

The aim of the research is the synthesis of sodium ammonium hydrogen phosphate and sodium dihydrogen phosphate based on purified extraction phosphoric acid. The acid was purified from accompanying impurities by precipitation methods using sodium carbonate and metasilicate, washed burnt phosphoconcentrate, barium carbonate, acid neutralization with gaseous ammonia. Pre-neutralization of the purified solution of monoammonium phosphate with sodium carbonate to the ratio Na2O:P2O5 = 0.44 and subsequent drying at a temperature of 50 °С allows to obtain sodium ammonium hydrogen phosphate tetrahydrate, and at 100 °С sodium dihydrogen phosphate monohydrate. The individuality and purity of the synthesized substances was established by the methods of X-ray diffraction, IR spectroscopy, thermogravimetry and scanning electron microscope.


1969 ◽  
Vol 90 (4) ◽  
pp. 380-383 ◽  
Author(s):  
Daido ISHII ◽  
Masashi GOTO ◽  
Eiji YOSHIKAWA

2020 ◽  
Vol 4 (442) ◽  
pp. 44-50
Author(s):  
Zhantasov K.T., ◽  
◽  
Shaimerdenova G.S., ◽  
Dzhanmuldaeva Zh.K., ◽  
Kadirbayeva A.A., ◽  
...  

1979 ◽  
Vol 15 (6) ◽  
pp. 469-471
Author(s):  
A. P. Konnov ◽  
E. I. Kovalev ◽  
L. P. Pertsev ◽  
Z. F. Kostenko ◽  
N. I. Tsybul'nik

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